The normal and differential titration curves of liganded and unliganded hemoglobin were measured at various KCl concentrations (0.1 to 2.0 M). In this range of KCl concentrations, the curves for deoxyhemoglobin showed no salt-induced pK changes of titratable groups. In the same salt concentration range oxyhemoglobin showed a marked change in titration behavior which could only be accounted for ...

This paper reports on the advantages and drawbacks of available test methods for the determination of chloride content in cementitious materials in general, and the application of Ag/AgCl chloride sensors in particular. The main factors that affect the reliability of a chloride sensor are presented. The thermodynamic behaviour of silver in the presence or absence of chloride ions is described a...

This paper reports on the advantages and drawbacks of available test methods for the determination of chloride content in cementitious materials in general, and the application of Ag/AgCl chloride sensors in particular. The main factors that affect the reliability of a chloride sensor are presented. The thermodynamic behaviour of silver in the presence or absence of chloride ions is described a...

This work is a preliminary examination of mechanistic issues on the comparative corrosion performance of regular epoxy-coated rebar (ECR) and dual polymer-zinc coated reinforcement (DCR) in simulated concrete pore solution with and without chloride ions, at polarizations from +100 mV to -1000 mV in the saturated calomel electrode (SCE) scale and exposure periods of 1 month or longer. Both mater...

Halide ions could be visualized via fluorescence quenching in microcolumn ion chromatography. The fluorescence of quinine sulfate, which was contained in an acidic eluent, was quenched by halide ions. The observed fluorescence quenching values increased in this order: iodide, bromide, and chloride. The present detection system was relatively sensitive to halide ions except for fluoride: other a...

Iron(III) hydrolysis in the presence of chloride ions yields akaganéite, an iron oxyhydroxide mineral with a tunnel structure stabilized by the inclusion of chloride. Yet, the interactions of this anion with the iron oxyhydroxide precursors occurring during the hydrolysis process, as well as its mechanistic role during the formation of a solid phase are debated. Using a potentiometric titration...

deterioration of concrete structures in the gulf region is a serious problem. penetration of chloride ion into concrete is responsible for such early deterioration. determination of chloride diffusion coefficient is an effective way to predict the service life of concrete structures. in order to investigate the performance of concrete mixtures in such environments, ordinary and silica fume conc...

Photocatalytic degradation of dichloroacetic acid (DCA) was studied in a continuous-flow set-up using a titanium microreactor with an immobilized double-layered TiO2 nanoparticle/nanotube film. Chloride ions, formed during the degradation process, negatively affect the photocatalytic efficiency and at a certain concentration (approximately 0.5 mM) completely stop the reaction in the microreacto...

The concentrations of malate, calcium ions, hydrogen ions, and chloride ions were measured in secretions coliected hetween June 1991 and May 1992 from the secretor\ trichomes of chickpea (Cicer arietinum L.|. The average maiate cisncentration was 114 mM and \ aried from 2 to 2K7 mM. the average chloride ion concentration «as 177 mM and varied trom 68 to 355 mM, and the average calcium ion conce...