A porphyrin-silicon nanowire (Si-NW) hybrid field-effect transistor is introduced. The hybrid device has separate electrical and optical gates surrounding the Si-NW channel. Porphyrin, a component of chlorophyll, is employed as an optical gate to modulate the potential of the Si-NW channel. Due to the independently formed hybrid gates, both optical and electrical excitation can effectively modu...

In an atomically thin-film/dielectric-substrate heterostructure, the elemental physical properties of the atomically thin-film are influenced by the interaction between the thin-film and the substrate. In this article, utilizing monolayer MoS(2) on LaAlO(3) and SrTiO(3) substrates, as well as SiO2 and Gel-film as reference substrates similar to previously reported work [Nano Res, 2014, 7, 561],...

the purpose of this investigation was directed to propose sensitive, accurate and reproducible methods of analysis that can be applied to determine distigmine bromide (dtb), cyclopentolate hydrochloride (cphc), diaveridine hydrochloride (dvhc) and tetrahydrozoline hydrochloride (thhc) drugs in pure form and pharmaceutical preparations via charge-transfer complex formation with 7,7,8,8-tetracyan...

the interaction between benzo-15-crown-5 (b15c5), dibenzo-18-crown-6 (db18c6), dibenzyl-daza-18crown-6 (dbzda18c6), n-phenyl-aza-15-crown-5 (npha15c5) and dibenzopyridine-18-crown-6 (dbpy18c6) with π-acceptor 2,3-dichloro-5,6-dicyanobenzoquinone (ddq) in chloroform solution was studied spectrophotometrically. the interaction of b15c5-ddq and db18c6-ddq caused the formation of 1:1 charge transfe...

We present time-resolved photoluminescence studies in conjunction with device characterization of a variety of heterojunctions with poly-(3-hexylthiophene), or P3HT, as a means to understand how exciton dynamics affect device performance. We find that blends of P3HT with the electron-transporting polymer CN-ether-PPV and with the fullerene derivative PCBM result in ~4-fold and ~15-fold improvem...

2014 A novel charge-coupled device structure operating by transferring charge packets on two distinct levels which are overlaid in the semiconductor bulk is described and analysed. This bulk-integrated device is twice as compact and has a reduced driving power consumption per bit, compared to conventional buried-channel CCD’s, still enjoying bulk-channel operation. Furthermore, the overlaid CCD...

Photoactive materials that are triggered by the irradiation of light to generate an electrical response provide an ecofriendly platform to afford efficient power sources and switches. A chemical assembly of well-known elements with aligned carbon nanotube bundles is reported here, which was employed to form an efficient photo-induced charge transfer device. The primary elements of this device a...

Electron-transfer reactions are fundamental to many practical devices, but because of their complexity, it is often very difficult to interpret measurements done on the complete device. Therefore, studies of model systems are crucial. Here the rates of charge separation and recombination in donor-acceptor systems consisting of a series of butadiyne-linked porphyrin oligomers (n = 1-4, 6) append...