Catalytic cracking of butene to propylene was carried out in a continuous-flow fixed-bed reactor over HZSM-5 catalysts modified by nickel and phosphorus. The structure and acidity of catalysts were measured by N2 adsorption, NH3-TPD and XPS. The results revealed that surface area and strong acid sites both decreased with increasing phosphorus loadings. The increment of phosphorus loadings reduc...

The paper presents designing of a robust fault diagnosis system for a catalytic cracking process using artificial neural networks. Identification of the considered process is carried out by using recurrent neural networks. To achieve a robust fault diagnosis system, an uncertainty associated with the model is also taken into account. Neural version of the Model Error Modelling is used to deal w...

This paper described the discovering process of some shortcomings of the conventional fluid catalytic cracking (FCC) process and the proposed two-stage riser (TSR) FCC process for decreasing dry gas and coke yields and increasing light oil yield, which has been successfully applied in 12 industrial units. Furthermore, the multifunctional two-stage riser (MFT) FCC process proposed on the basis o...

Metal accumulation at the catalyst particle surface plays a role in particle agglutination during fluid catalytic cracking.

Three high-silica mordenite zeolites differing in SiO440, ratio were prepared by direct synthesis without using any template. The products Si02/A120, ratio is influenced by the starting gel composition. This ratio is increased upon ion-exchange with NH,Cl and subsequent calcination to prepare protonic mordenite. The protonic mordenites with Si02/A1203ra tios of 14.6,29.2 and 34.6 were chara...

Feedstock conversion and yield products are studied through a 3Dmodel simulating the main reactor of the fluid catalytic cracking (FCC) process. Computational fluid dynamic (CFD) is used with Eulerian-Eulerian approach to predict the fluid catalytic cracking behavior. The model considers 12 lumps with catalyst deactivation by coke and poisoning by alkaline nitrides and polycyclic aromatic adsor...

In this paper, fuzzy logic control of a fluid catalytic cracking unit (FCCU) is proposed. Fluid catalytic cracking (FCC) process is a unit that converts heavy distillates like gas oil or residues to gasoline and middle distillates using cracking catalyst. About 45% of worldwide gasoline production comes from FCC processes and its ancillary units. Since a typical FCC unit can process a large amo...