Applying the cw laser fluorescence method, the cross sections for the fine structure mixing and quenching of the Cs 6P state, induced by collisions with ground-state caesium atoms and molecules, have been measured. Caesium atoms were optically excited to the 5DJ states via quadrupole-allowed 6S1/2 → 5DJ transitions, while the resonance states were populated by the radiative and collisional 5DJ ...

Applying the cw laser absorption and fluorescence method the cross sections for the fine-structure mixing and quenching of the caesium 5DJ states have been measured in pure caesium vapour. Caesium atoms were optically excited to the 5D5/2 state via the quadrupole-allowed 6S1/2 → 5D5/2 transition. The ground-state caesium density N0, obtained from the absorption at the pumped quadrupole transiti...

1. The method of sedimentation equilibrium in a gradient of caesium chloride has been applied to the preparation of blood-group-specific glycoproteins from human ovarian-cyst fluids: it is shown that virtually complete separation from contaminating protein is easily accomplished in a single step. 2. The glycoproteins isolated in this way have been characterized by analytical density-gradient ex...

A novel dipole force trap was developed for trapping caesium atoms in the lower hyperfine level of the ground state and in preliminary experiments a cloud of ≈1000 atoms was trapped. The viability of the trap is discussed, including suggestions for amendments to the trap design and problems that might occur which are intrinsic to the caesium atom.

A fruitful combination of potentiometry, absorption spectrophotometry, ESMS and 1H NMR enabled the characterisation of two caesium complexes with norbadione A and the determination of the respective stability constants of a mononuclear and a dinuclear caesium complex at pH approximately 6; a preliminary study allowed the assignment of five protonation sites of this pigment; a positively coopera...

The title compound, penta-caesium nona-stannide hydroxide tetra-ammonia, crystallized from a solution of CsSnBi in liquid ammonia. The Sn9 (4-) unit forms a monocapped quadratic anti-prism. The hydroxide ion is surrounded by five caesium cations, which form a distorted quadratic pyramidal polyhedron. A three-dimensional network is formed by Cs-Sn [3.8881 (7) Å to 4.5284 (7) Å] and Cs-NH3 [3.276...

We have observed that the collisional frequency shift in primary caesium fountain clocks varies with the clock state population composition and, in particular, is zero for a given fraction of the |F=4,mF=0) atoms, depending on the initial cloud parameters. We present a theoretical model explaining our observations. The possibility of the collisional shift cancellation implies an improvement in ...

Vigorous reaction of barbituric acid with caesium hydroxide in water resulted in an unexpected coupling product, 5-hydroxyhydurilic acid, complexed to caesium, giving poly[[caesium-mu5-5-hydroxyhydurilato] hemihydrate], {[Cs(C8H5N4O7)].0.5H2O}n. This was obtained in two different polymorphic forms, depending on the method of crystal growth. Slow solvent evaporation yielded an orthorhombic polym...