In transport experiments through columns packed with naturally Fe/Al oxide-coated quartz sand, breakthrough curves (BTCs) of natural organic matter (NOM) displayed strong and persistent power law tailing that could not be described by the classical advection-dispersion equation. Tailing was not observed in BTCs for a nonreactive tracer (sulforhodamine B); therefore, the anomalous transport is a...

We present an exact expression for the upscaled dynamic dispersion coefficient (D) for one-dimensional transport by Hagen-Poiseuille flow which is the basis for modeling transport in porous media idealized as capillary tubes. The theoretical model is validated by comparing the breakthrough curves (BTCs) from a 1D advection-dispersion model with dynamic D to that from direct numerical solutions ...

[1] This study proposed a new mobile‐immobile model (MIM) to describe reactive solute transport with scale‐dependent dispersion in heterogeneous porous media. The model was derived from the conventional MIM but assumed the dispersivity to be a linear or exponential function of travel distance. The linear adsorption and the first‐order degradation of solute were also considered in the model. The...

Membrane chromatography (MC) is gaining wider acceptance in downstream processing of biopharmaceuticals. MC offers the advantage of higher operational flow-rates and thus, provides an attractive alternative to traditionally employed packed bed chromatography. With increased commercial usage, in-depth understanding of different mechanisms within MC capsules is desirable in order to achieve optim...

Three new fully implicit methods which are based on the (5,5) Crank–Nicolson method, the (5,5) N-H (Noye–Hayman) implicit method and the (9,9) N-H implicit method are developed for solving the heat equation in two dimensional space with non-local boundary conditions. The latter is fourth-order while the others are second-order. While the implicit methods developed here, like the scheme based on...

Gallbladder cancer (GBC) represents the most common and aggressive type among the biliary tree cancers (BTCs). Complete surgical resection offers the only chance for cure; however, only 10% of patients with GBC present with early-stage disease and are considered surgical candidates. Among those patients who do undergo "curative" resection, recurrence rates are high. There are no established adj...

The activity of the Polish Blood Transfusion Service (BTS) is based on the Public Blood Transfusion Service Act sanctioned by the Polish Parliament. There are 21 regional Blood Transfusion Centers (BTCs), 1 Military BTC and 1 BTC of the Ministry of Internal Affairs. The Institute of Hematology and Transfusion Medicine (IHTM) is responsible for issuing guidelines for blood transfusion medicine. ...

Discrete-fracture and dual-porosity models are infrequently used to simulate solute transport through fractured unconsolidated deposits, despite their more common application in fractured rock where distinct flow regimes are hypothesized. In this study, we apply four fracture transport models--the mobile-immobile model (MIM), parallel-plate discrete-fracture model (PDFM), and stochastic and det...

Predicting the fate and movement of contaminant in soils and groundwater is essential to assess and reduce the risk of soil contamination and groundwater pollution. Reaction processes of contaminant often decreased monotonously with depth. Time-dependent input sources usually occurred at the inlet of natural or human-made system such as radioactive waste disposal site. This study presented a on...

Displacement studies on leaching of bromide and two pesticides (atrazine and isoproturon) were conducted under unsaturated steady state flow conditions in 24 small undisturbed soil columns (5.7 cm in diameter and 10 cm long) each collected from two sites differing in soil structure and organic carbon content in North Germany. There were large and irregular variabilities in the characteristics o...