The kinetic behavior of a fixed-bed adsorber can be explained and the characteristic breakthrough curve of the adsorption phenomena can be obtained through mathematical models. In the earlier models, the kinetics is explained using a mathematical model that takes into account of external and internal masstransfer resistances with a nonideal plug flow behavior. The variation of fluid velocity al...

We present an experimental and theoretical study of the breakthrough performance of the flexible metal-organic framework Cu(bpy)2(BF4)2 (bpy = 4,4'-bipyridine), termed ELM-11. Pure CO2, He, CH4, and N2 gases, as well as binary gas mixtures of those species, were used to perform breakthrough experiments on ELM-11. ELM-11 exhibits a stepped breakthrough curve for CO2 not seen in rigid adsorbents....

Sorption characteristics of Co which is rather troublesome nuclide from the aspect of low level radioactive waste disposal was studied. By use of ultraviolet-visible spectrophotometer, coexistence of ionic and colloidal cobalts was verified in aqueous solution with pH>7. Column test was carried out with pH=8.75 and it showed that breakthrough curve obtained consists of two types of curves due t...

Dynamic modeling and simulation of fixed bed adsorption process was carried out by explaining the behavior of breakthrough curve parameter. Adsorption of sulfur compound, present in road fuel, has posed a great challenge. A model of fixed bed adsorption of benzothiophene from fuel was formulated with non-ideal plug flow behavior and considered velocity variation along a column. The model was so...