1,2,3-Triazoles bearing additional functional groups have found applications as the ligands in catalysis of a broad scope reactions, synthesis transition metals complexes for various practicable purposes, and design metal-based drugs. Triazolyl accelerating CuAAC such TBTA TTTA, are nowadays commonly used organic synthesis, search novel with less complicated structure represents an important ta...

The present study, for the first time, presents a feasible protocol for the preparation of β-cyclodextrin/ imidazolium based dicationic ionic liquid, [βCD/Im](OTs)2, and its application as an efficient and eco-friendly microvessel and host ionic liquid system for the regioselective ring opening of the epoxides in water. No evidence for the formation of diol by-products or side reacti...

In this protocol, 3-(2-carboxybenzoyl)-1-methyl-1H-imidazol-3-ium chloride [Cbmim]Cl and sulfonic acid functionalized pyridinium chloride [pyridine-SO3H]Cl as a new, reusable, and green Brønsted acidic ionic liquid (BAIL) catalyst were synthesized and successfully used for the one-pot ring opening of epoxide with sodium azide (NaN3) in water at room temperature. Epoxides under ring-opening easi...

The regioselective opening of epoxides with organotin oxides 1 and 2, in presence of halogenated alcohols was developed, yielding the halohydrin derivatives. Introduction Epoxides are among the most versatile intermediates in organic chemistry due to the particular polarity and strength of their three member ring. Those characteristics make them in a very suitable substrate to the attack or man...