Results of an experimental study of volume osmotic flows in a single-membrane osmotic-diffusive cell, which contains a horizontal, microporous, symmetrical polymer membrane separating water and binary or ternary electrolyte solutions are presented. In the experimental set-up, water was placed on one side of the membrane. The opposite side of the membrane was exposed to binary or ternary solutio...

in this work we have applied the dense system equation of state (dseos) to electrolyte solutions. we have found that this equation of state can predict the density of electrolyte solutions very accurately. it has been tested for different electrolytes solutions at different temperatures and compositions. a hypothetical binary model has been applied to find the dependencies of parameters of this...

systematic studies on the vapor-liquid equilibria (vle) and conductometric properties of aqueous solutions of model surface-active ionic liquid 1-dodecyl-3-methylimidazolium bromide ([c12mim]br) are performed in the absence and presence of a large series of electrolytes in order to achieve a deeper understanding about the molecular mechanism behind the specific salt effect on the aggregation be...

In this work the effect of electrolytes on hydrate formation was investigated. To do so, a new model was used in predicting the hydrate formation conditions in presence of both single and mixed electrolyte solutions. The new model is based on the van der Waals - Platteeuw hydrate equation of state. In order to evaluate the values for the activity of water in electrolyte solutions t...

The development of spectroscopic and electrochemical devices that can accommodate very small samples is of considerable importance to many areas of science and technology. We report here on the design and characteristics of a simple apparatus for the electrochemical and spectroelectrochemical analysis of submicroliter aqueous samples. The device is easily assembled from common laboratory materi...

In this work we have applied the Dense System Equation of State (DSEOS) to electrolyte solutions. We have found that this equation of state can predict the density of electrolyte solutions very accurately. It has been tested for different electrolytes solutions at different temperatures and compositions. A hypothetical binary model has been applied to find the dependencies of parameters of ...

In this work, the performance of four electrolyte models for prediction the osmotic and activity coefficients of different aqueous salt solutions at 298 K, atmospheric pressure and in a wide range of concentrations are evaluated. In two of these models, (electrolyte Non-Random Two-Liquid e-NRTL and Mean Spherical Approximation-Non-Random Two-Liquid MSA-NRTL), association between ions of opposit...

In this work, reactive absorption of gases in aqueous electrolyte solutions has been investigated resulting in the development of a procedure in order to calculate the concentrations of ionic and molecular species in the liquid phase. Two duplicate experiments were conducted to investigate simultaneous reactive absorption of ammonia and carbon dioxide in partially carbonated ammonia solutio...