in this work, we consider each normal alkane as a hypothetical mixtureof methyland methylene groups, in which the interaction potential of each pair is assumed to be the average effective pair potential. then, the lir equation of state (eos) is extended for such a hypothetical mixture. also, three basic compounds, namely, propane, n-butane and cyclohexane, are used to obtain the contribution of...

Cladospofium resinae was grown in submerged cultures on glucose; on Jet-A commercial aviation fuel; and on a series of n-alkanes, n-decane through n-tetradecane. Cell yield was greatest on glucose and least on Jet-A; n-alkanes were intermediate. Among n-alkanes cell yield decreased as chain length increased, except for n-dodecane, which supported less growth than n-tridecane or n-tetradecane. T...

Cladospofium resinae was grown in submerged cultures on glucose; on Jet-A commercial aviation fuel; and on a series of n-alkanes, n-decane through n-tetradecane. Cell yield was greatest on glucose and least on Jet-A; n-alkanes were intermediate. Among n-alkanes cell yield decreased as chain length increased, except for n-dodecane, which supported less growth than n-tridecane or n-tetradecane. T...

The fragmentation of normal alkanes during the cracking oil under geochemical conditions with high thermal stress is important for preservation crude oils in reservoirs and formation gaseous hydrocarbons. In this study, kinetics behavior, mechanisms, products n-tetradecane pyrolysis were investigated using reactive molecular dynamics (ReaxFF MD) simulations at temperatures (2000K∼3000 K). proce...

Though the lower n-alkanes are considered the most degradable components of crude oil, our experiments with microcosms simulating oiled beaches showed substantial depletion of fluorene, phenanthrene, dibenzothiophene, and other PAH in control treatments consisting of raw seawater cycled through the microcosms over a 30-day period. PAH was not detectable in pooled test system effluents. To resol...

We report the first extensive study of the spatial distribution and source apportionment of aliphatic hydrocarbons in soils from the Beijing outskirts. Mixed soil samples (5–30 cm depth) were collected for the quantitative determination of n-alkanes, isoprenoids, unresolved complex mixtures and the qualitative determination of hopanes and steranes. The total concentrations, including n-alkanes ...

The growth of secondary organic aerosols (SOA) is a vital cause the outbreaks winter haze in North China. Intermediate volatile compounds (IVOCs) are important precursors SOA. Therefore, chemical characteristics, source, and SOA production IVOCs during episodes have attracted much attention. Hourly time resolution IVOC samples two collected Hebei Province China were analyzed this study. Results...

Ab&r&-Quartz crystals from calcite veins of unknown age in Precambrian metasedimentary rocks at Geiaus No. 6 and Aukam farms in South-West Africa contain both primary and secondary inclusions filled with one or a variable combination of: organic liquid, moderately saline aqueous liquid, dark-colored solid, and vapor. Analysis of these materials by microscopy and by gas chromatography and maas s...

[1] Long-chain, odd-carbon-numbered C25 to C35 n-alkanes are characteristic components of epicuticular waxes produced by terrestrial higher plants. They are delivered to aquatic systems via eolian and fluvial transport and are preserved in underlying sediments. The isotopic compositions of these products can serve as records of past vegetation. We have developed a rapid method for stable carbon...