The development of controlled-release formulations of alachlor to diminish its leaching in sandy soils, avoiding groundwater contamination and maintaining its efficacy, was studied. For this purpose, ethylcellulose (EC) microencapsulated formulations (MEFs) of alachlor were prepared under different conditions and applied to soil columns to study their mobility. The results show that in all case...

The Cu/Al2O3 catalyzed ozonation for degrading an endocrine disruptor—alachlor in water was investigated. The Cu/Al2O3 powders were coated on a cordierite honeycomb column, which was taken as the reactor of catalytic ozonation of alachlor. Additional uncatalyzed experiments were carried out and the results were compared to those of the catalytic runs. The experimental results demonstrated that ...

This study investigated the phytotoxicity of herbicides applied singly or as mixtures to different crops under greenhouse conditions. Growth inhibition of the crops was taken as an indicator of phytotoxicity. Phytotoxicity of mixtures was estimated by calculating EC50 value in toxic units. EC50 (mg/kg soil) of Alachlor, Bromacil and/or Diuron were: 11.37, 4.77, 1.64, respectively, on melon; 0.1...

The in vivo rates of uptake and detoxification of alachlor and metolachlor were determined using Pioneer corn 3320 seedlings. Equal amounts of the radiolabeled herbicides were applied to etiolated coleoptiles and, at various intervals after treatment, the unabsorbed radioactivity was removed and quantified. Analysis of 80% methanol extracts by reverse phase liquid chromatography showed no signi...

Fe-TiO2 on granular activated carbon support was synthesized via hydrothermal method without calcination. The crystalline phases were identified using X-ray diffraction whereas the surface morphologies were examined using scanning electron microscopy. Peaks of anatase TiO2 and graphite were present in the Fe-TiO2-GAC sample. Comparisons of the surface features of GAC and Fe-TiO2-GAC show that F...

The degradation of alachlor has been investigated using sonolysis (US), photocatalysis (UV) and sonophotocatalysis (US/UV) using three photocatalyst viz. TiO2 (mixture of anatase and rutile), TiO2 (anatase) and ZnO. The effect of photocatalyst loading on the extent of degradation of alachlor has been investigated by varying TiO2 (both types) loading over the range of 0.01 g/L to 0.1 g/L and ZnO...

BACKGROUND The herbicide alachlor (2-chloro-2'6'-diethyl-N-methoxymethylacetanilide) has been known as a probable human carcinogen, and the MCL (minimum contamination level) for drinking water has been set at 2 μg L-1. Therefore, the advanced methods for effectively removing it from water are a matter of interest. Catalyzed ozonation is a promising method for refractory organics degradation. Cu...

The effects of a single pulse, 21-d exposure of the commonly used herbicide alachlor (2-chloro-2′, 6′-diethyl-N-methoxymethyl acetanilide) on an algal community from a typical agricultural stream in Nebraska were studied using 18 stream microcosms located in a greenhouse, at six alachlor concentrations (0, 1, 10, 30, 100, and 1,000 μg/L). Effects of alachlor exposure at 1.0 μg/L were not signif...

The application rates for conventional herbicide formulations are generally greater than the recommended dosage, in order to overcome losses from degradation, leaching, volatilization, and sorption during the time needed for weed control. All these factors have encouraged the development of controlled release formulations (CRFs), which can reduce herbicides levels in the environment since less ...

The effects of alachlor (2.25 kg a.i./ha) and fenamiphos (2.25 kg a.i./ha) on the penetration and development of Heterodera glycines were examined on Glycine max cultivars Deltapine 105 planted 29 April, 29 May, and 29 June 1986 and Deltapine 105 and Centennial planted 15 May, 15 June, and 15 July 1987. Penetration was lowest on the third planting of soybeans and on fenamiphos-treated plants. D...