Oils of vegetable origin are of great importance in food, soap, and cosmetic industries and they may also be used as lubricants and raw materials for biodiesel production depending on their viscosity and thermal stability. This work provides insight into the fatty acid components, physicochemical properties and thermal stability of some refined vegetable oils. The Saponification values, peroxid...

Schiff base complexes of transition metals are of particular interest to inorganic chemists because of their structural, spectral and chemical properties, which are often strongly dependant on the nature of the ligand structure. Large number of metal (II) complexes with Schiff-base ligands has been extensively studied for their interesting structural specialties, applications and properties. Th...

This paper presents the results of a study of the prediction of the entropy growth within an internal free shear layer of an ideal gas flow downstream of a sudden expansion of the flow area. The objective of the study is exploratory in nature by invoking concepts from information theory to connect the deterministic prediction of the spectral entropy growth within the shear layer to the experime...

Entropic effects have often been invoked to explain the extraordinary catalytic power of enzymes. In particular, the hypothesis that enzymes can use part of the substrate-binding free energy to reduce the entropic penalty associated with the subsequent chemical transformation has been very influential. The enzymatic reaction of cytidine deaminase appears to be a distinct example. Here, substrat...

The conditions inside next-generation nuclear reactors are likely to be extreme. High-performance materials will required, and there is still great scope for developing new improved alloys. High-entropy alloys (HEAs) potential candidates, it that such need based around low-activation elements tend form body-centred cubic structures. Whilst have been a number of investigations assessing the capa...

The present study combines density functional theory (DFT) based calculations and experimental techniques to investigate the formation of equiatomic quaternary “low-activation" high entropy alloys (HEAs) for nuclear fission/fusion applications. DFT are adopted screen possible single-phase ternary in chemical space consisting low-activation elements (Ti, V, Cr, Mn, Fe, Ta W). results indicate th...

thermal rearrangement of 7,7-dichloro-[a,c]-dibenzo-[4,1,0]-bicycloheptane (1) to 5,6-dichloro-5hdibenzo-[a,c]-cycloheptene (2) was studied in the solid phase and in solvents with different polarities. thefirst-order constants at various temperatures for the rearrangement process were evaluated from theabsorption time data. the activation parameters for this rearrangement were obtained from the...

BACKGROUND In ventricular scar, impulse spread is slow because it traverses split and zigzag channels of surviving muscle. We aimed to evaluate scar electrograms to determine their local delay (activation time) and inequality in voltage splitting (entropy), and their relationship to channels. We reasoned that unlike innocuous channels, which are often short with multiple side branches, ventricu...

Subcritical crack growth in fused silica is treated as a stress assisted chemical reaction between water and strained bonds at the crack tip. In this work, the kinetics of the reaction is modeled by assuming the stress reduces the energy barrier of the activated complex by affecting both the activation enthalpy and entropy, where the stress dependence can take different forms. This theory is co...