aluminum sulfate nano structures have been prepared by solution combustion synthesis using aluminum nitrate nonahydrate (al(no3)3.9h2o) and ammonium sulfate ((nh4)2so4). the resultant aluminum sulfate nano structures were calcined at different temperatures to study thermal  decomposition of aluminum sulfate. the crystallinity and phase of  the as-synthesized and calcined samples were characteri...

The reaction of γ-alumina with tetraethylorthosilicate (TEOS) vapor at low temperatures selectively yields monomeric SiO(x) species on the alumina surface. These isolated (-AlO)3Si(OH) sites are characterized by PXRD, XPS, DRIFTS of adsorbed NH3, CO, and pyridine, and (29)Si and (27)Al DNP-enhanced solid-state NMR spectroscopy. The formation of isolated sites suggests that TEOS reacts preferent...

DRIFTS, was used to study small organic molecules, with and without functional groups, adsorbed to the surface of γ-alumina and kaolinite clay from a non-polar solvent. Adsorbed water is present on the surface of both minerals and this influences the adsorption of organic molecules from, the non-polar solvent, onto the mineral surface, particularly the interaction of polar functional groups wit...

Aluminum sulfate nano structures have been prepared by solution combustion synthesis using aluminum nitrate nonahydrate (Al(NO3)3.9H2O) and ammonium sulfate ((NH4)2SO4). The resultant aluminum sulfate nano structures were calcined at different temperatures to study thermal  decomposition of aluminum sulfate. The crystallinity and phase of  the as-synthesized and calcined samples were char...

Imidazolium bromide-based ionic liquids bearing phosphonyl groups on the cationic part were synthesized and grafted on γ-alumina (γ-Al₂O₃) powders. These powders were prepared as companion samples of conventional mesoporous γ-alumina membranes, in order to favor a possible transfer of the results to supported membrane materials, which could be used for CO₂ separation applications. Effective gra...

Abstract This study examined the influence of crystallinity added nano-alumina on sulfate resistance ordinary Portland cement (OPC) paste. Two crystalline types nano-aluminas (α-and γ-phase) were incorporated in pastes, which exposed to solution. In results, both paste samples having α- and γ-phase aluminas had accelerated compressive strength loss increased length expansion compared sample wit...

The role of iron in two modes of integration into alumina catalysts was studied at 0.39 wt% Fe and tested in trichloroethylene combustion. One modified alumina was synthesized using the sol-gel method with Fe added in situ during hydrolysis; another modification was performed using calcined alumina, prepared using the sol-gel method and impregnated with Fe. Several characterization techniques w...

Structural information is important for understanding surface adsorption mechanisms of contaminants on metal (hydr)oxides. In this work, a novel technique was employed to study the interfacial structure of arsenate oxyanions adsorbed on γ-alumina nanoparticles, namely, differential pair distribution function (d-PDF) analysis of synchrotron X-ray total scattering. The d-PDF is the difference of ...

The dependence of aluminum (Al) melting temperature on particle size was studied using a differential scanning calorimeter and thermogravitmetric analyzer for particles encapsulated in an oxide shell. Pressure generation within the Al core leads to an increase in melting temperature in comparison with traditional melting temperature depression calculated using the Gibbs−Thomson equation. On the...

Abstract The mechanical properties of ceramic granular γ-alumina, including resistance and stability, are examined using Nano indentation scratch tests. In so doing, surface morphology, kind material used, topography, roughness the evaluated a scanning electron microscope, energy-dispersive X-ray spectroscopy atomic force microscopy. To achieve these objectives, initial step involves synthesis ...