In the present study, the effect of alumina on the pore structure and hydrothermal stability of nanostructured silica was investigated. SiO2 and SiO2-15wt%Al2O3 membranes were prepared by dip coating on mesoporous γ-Al2O3 coated macroporous α-alumina support. The particle sizes of sol were increased by adding of alumina to silica...

Ferritic alumina-forming alloys showed high corrosion resistance to molten carbonates by forming a protective α-LiAlO2 scale at their surface. In this work, four ferritic were pre-oxidised before exposure (Li,Na,K)2CO3-melt 800 °C for 1000 h. Only outer transient alumina, such as γ-alumina, reacts with the melt, LiAlO2. At same time, innermost α-Al2O3 remains intact. α-Al2O3, well α-LiAlO2, are...

Investigations of activation energy barriers for Al surface hopping on α-Al2O3 (0001) surfaces have been carried out by means of first-principles density functional theory calculations and the nudged elastic band method. Results show that surface diffusion on the (most stable) Al-terminated surface is relatively fast with an energy barrier of 0.75 eV, whereas Al hopping on the O-terminated surf...

polycrystalline mfi zeolite membranes were prepared on α-alumina tubular support by hydrothermal treatments at 413 k. the synthesized zeolite membranes were characterized by xrd, sem and single gas permeation. the influence of hydrothermal treatment steps and the calcination time on the zeolite layer formation were investigated. mfi zeolite membrane prepared by four subsequent hydrothermal trea...

Polycrystalline MFI zeolite membranes were prepared on α-alumina tubular support by hydrothermal treatments at 413 K. The synthesized zeolite membranes were characterized by XRD, SEM and single gas permeation. The influence of hydrothermal treatment steps and the calcination time on the zeolite layer formation were investigated. MFI zeolite membrane prepared by four subsequent hydrothermal ...

ru/al2o3 catalysts were prepared by conventional incipient wetness impregnation as well as colloid deposition of rucl3 precursor via in situ reduction with ethylene glycol (polyol) method on alumina support. the samples were characterized by tem, xrd and tpr techniques. the catalytic performance tests were carried out in a fixed-bed micro-reactor under different operating conditions. ethylene g...

An efficient and green protocol for the synthesis of αaminonitriles derivatives by one-pot reaction of different aldehydes with amines and trimethylsilyl cyanides has been developed using natural alumina, alumina sulfuric acid (ASA), nano-γ-alumina, nanoalumina sulfuric acid (nano-ASA) under microwave irradiation and solvent-free conditions. The advantages of methods are short reaction times, h...

To discuss the potential role of the support for iridium catalyst, we have proceeded to prepare a series of supported catalysts with the same active phase content, but different silica content, to elucidate the changes in surface structure and the reaction process of hydrous hydrazine decomposition on catalyst. The obtained iridium catalysts contained 20 wt% of nanoparticles dispersed on spheri...

background: autophagy as a cellular pathway facilitates several immune responses against infection. it also eliminates invading pathogens through transferring content between the cytosol and the lysosomal vesicles and contributes to the cross-presentation of exogenous antigens to t lymphocytes via mhc class i pathway. autophagy induction is one of the main targets for new drugs and future vacci...

Alumina is one of the most widely used adsorbent for removal of dissolved pollutants from waste water. Various chemical species, especially ions, are known to be adsorbed onto alumina. On the other hand, alumina is a typical support for catalysts. Many kinds of metal supported catalysts are prepared using alumina as their support. These two roles of alumina, i.e., as adsorbent and support, are ...