The use of H-ZSM-5 with various binders (Al 2 O 3 , SiO and kaolinite, 10 wt% on catalyst formulation) for the catalytic conversion glycerol to bio-based aromatics (GTA) was investigated in a continuous bench-scale unit at pyrolysis temperature 450 °C, upgrading 500 WHSV pure 1 h ?1 atmospheric pressure, their performance compared (SiO /Al molar ratio 28). latter gave peak BTX carbon yield ca. ...

The realization of biofuels and chemicals requires the development highly active selective catalysts, which are resistant to deactivation. A conventional ZSM-5 (SiO2/Al2O3 = 30) was modified with 0.2 M NaOH generate a mesoporous zeolite support. parent zeolite, mic-ZSM-5, hie-ZSM-5, silica support, SiO2, were impregnated 5% nickel characterized using X-ray powder diffraction (XRD), Brunauer–Emm...

In this study, a novel dispersive micro-solid phase extraction (D-μSPE) technique with H-ZSM-5 zeolite as an adsorbent was developed for the determination of 21 trace pesticides in tea beverages. The adsorption and desorption zeolites were investigated based on structural characteristics properties similar to those H-beta zeolites. combination adsorbates, it explained that reaction occurred mic...

A novel modified Ni-ZSM-5 nanozeolite was fabricated via an organic template-free hydrothermal route. The average particle size of Ni-ZSM-5 nanozeolite was calculated to be 85 nm by scanning electronic microscopy. Then, Carbon paste electrode (CPE) was modified by Ni-ZSM-5 nanozeolite and Ni2+ ions were then incorporated to the nanozeolite matrix. Electrochemical behavior of this electrode was ...

ZSM-5- and NaY-coated MCF materials as new acid catalysts for conversion of bulky molecules were prepared by the coating procedure using diluted clear zeolite gel solutions. The resulting materials have high acidity and improved steam stability as compared to that of the corresponding MCF aluminosilica. This could be due to the zeolitic nature and relative hydrophobicity of the mesopore surface.

The hierarchically porous and iron-functionalized zeolite ZSM-5 has been fabricated as a Fenton photocatalyst by a facile post-treatment process, which exhibits an excellent visible-light catalytic property in the adsorption/degradation of organic pollutants under mild reaction conditions.

Catalytic fast co-pyrolysis of sewage sludge and sawdust was performed using Py/GC-MS for pyrolytic product upgrades. Metal oxides (NiO MoO3) ZSM-5 catalysts had been introduced into single catalytic pyrolysis. The combination NiO + MoO3 in mixed metal (MMOs) modified with under a dual-catalyst different layouts. In the pyrolysis process, specifically promoted formation phenols, ketones, furans...

With growing interest for the use of one-dimensional (1-D) zeolites in separation and reaction processes, the need to understand diffusion and transport properties of molecules within the channels of these materials is becoming more eminent. The mechanism used to describe passage of molecules inside narrow 1-D micropores is called single-file diffusion. Typically, this behavior is observed with...

BIOFUELS PRODUCTION FROM HYDROTREATING OF VEGETABLE OIL USINGSUPPORTED NOBLE METALS, AND TRANSITION METAL CARBIDE AND NITRIDEbyHUALI WANGMay 2012Advisors: Dr. K. Y. Simon Ng and Dr. Steven O. SalleyMajor: Chemical EngineeringDegree: Doctor of PhilosophyThe focus of this research is to prepare non-sulfided hydrotreating catalysts, supportednoble metal and ...