The oxygen tracer diffusion coefficient describing transport along nano-/microscaled YSZ/Sc2O3 multilayers as a function of the thick-ness of the ion-conducting YSZ layers has been measured by isotope exchange depth profiling (IEDP), using secondary ion mass spec-trometry (SIMS). The multilayer samples were prepared by pulsed laser deposition (PLD) on (0001) Al2O3 single crystalline substrates....

Effective and scalable recycling strategies for the recovery of critical raw materials are yet to be validated solid oxide cells (SOCs) technologies. The current study aimed at filling this gap by developing optimized processes Yttria-stabilized Zirconia (YSZ) from End-of-Life (EoL) SOC components, in view using recovered ceramic phase cell re-manufacturing. A multi-step procedure, including mi...

Solid oxide fuel cell (SOFC) cathodes were prepared by infiltration of 35 wt % La0.8Sr0.2FeO3 (LSF) into porous scaffolds of three, zirconia-based electrolytes in order to determine the effect of the ionic conductivity of the electrolyte material on cathode impedances. The electrolyte scaffolds were 10 mol % Sc2O3-stabilized zirconia (ScSZ), 8 mol % Y2O3-stabilized zirconia (YSZ), and 3 mol % Y...

Abstract This work focuses on improving the durability of Ni/yttria-stabilized zirconia (YSZ) fuel electrode-supported solid oxide cells under reversible operation mode by infiltrating nano-sized electrocatalysts into both electrodes. The resulting cell consists a CGO (Gd-doped CeO 2 ) scaffold-based oxygen electrode that is infiltrated with LSC (La 0.6 Sr 0.4 CoO 3-δ and CGPO (Gd, Pr-co-doped ...

A bimodular planar O2 sensor was fabricated using NiO nanoparticles (NPs) thin film coated yttria-stabilized zirconia (YSZ) substrate. The thin film was prepared by radio frequency (r.f.) magnetron sputtering of NiO on YSZ substrate, followed by high temperature sintering. The surface morphology of NiO NPs film was characterized by atomic force microscope (AFM) and scanning electron microscope ...

Materials for applications in hostile environments, such as nuclear reactors or radioactive waste immobilization, require extremely high resistance to radiation damage, such as resistance to amorphization or volume swelling. Nanocrystalline materials have been reported to present exceptionally high radiation-tolerance to amorphization. In principle, grain boundaries that are prevalent in nanoma...

The changes in the surface phase and the morphology of nickel–yttria stabilized zirconia (YSZ) cermet anodes for solid oxide fuel cells (SOFCs) upon exposure to a fuel containing 100 parts per million (ppm)-level hydrogen sulfide (H2S) at elevated temperatures were investigated using in situ Raman microspectroscopy as well as ex situ techniques such as X-ray diffraction (XRD), scanning electron...