This thesis deals with the synthesis and characterization of novel polyhydroxyl surfactants. The first part describes the synthesis of a number of stereoisomers of a polyhydroxyl surfactant, and the second part concerns surface chemical characterization. A stereodivergent route for preparation of the hydrophilic head group was developed, featuring consecutive stereoselective dihydroxylations of...

This paper deals with the propagation of magneto-thermo Rayleigh waves in a homogeneous viscoelastic half-space under initial stress. It has been observed that velocity of Rayleigh waves depends on viscosity, magnetic field, temperature and initial stress of the half-space. The frequency equation for Rayleigh waves under the effect of magnetic field, stress and temperature for both viscoelastic...

The newest results concerning the biological activity and environmental fate of anionic surfactants are collected and critically evaluated. The chemical and physicochemical parameters related to the biological activity and the field of application are briefly discussed. Examples on the effect of anionic surfactants on the cell membranes, on the activity of enzymes, on the binding to various pro...

The investigation of surface tension is a very important task for gas hydrate studying. Surfactants can effectively reduce the surface tension, improve the gas storage capability of hydrate and increase the formation rate, shorten the induction time. The objective of this study were to obtain a better understanding of the role of surface tension on hydrate formation and build gas hydrate models...

New quaternized oligomeric surfactants containing 4 or 8 alkyl chains were synthesized using ethylenediamine or poly(amidoamine) dendrimers as the central scaffold. Electrical conductivity, surface tension, and pyrene fluorescence measurements, as well as dynamic light scattering were used to characterize their properties. In addition, the dependence of these properties on the alkyl chain lengt...

Recent years have seen increasing worldwide interest in the use of viscoelastic coagulation monitoring tests, performed using devices such as ROTEM and TEG. The use of such tests to guide haemostatic therapy may help reduce transfusion of allogeneic blood products in bleeding patients and is supported in European guidelines for managing trauma and severe perioperative bleeding. In addition, vis...

The adhesive performances of a PSA (Pressure Sensitive Adhesive) are attributed to their viscoelastic properties. In this paper we analyze the viscoelastic behavior of different PSAs having substantially similar adhesive performance. Linear and non linear analyses were performed using small amplitude oscillatory shear tests and tensile stress-strain tests, respectively. It is shown that linear ...

needle insertion is a minimally invasive technique in diagnosing and treating tumors. however, to perform a surgery accurately, the tissue should have minimum amount of displacement during needle insertion so that it reaches the target tissue. therefore, the tissue membrane has to move less to decrease rupturing under the membrane. in this study, the effect of different design parameters on dis...

It is known that cationic surfactants have an antimicrobial effect and act as enhancers. This paper studies three cationic surfactants from the group of alkyldimethylbenzylammonium chlorides (dodecyl-, tetradecyl-, and hexadecyl). Interest is focused on the association of the surfactants with respect to temperature, partition balances and their influence on drug release, rheological properties,...