نتایج جستجو برای: vapor liquid equilibrium vle
تعداد نتایج: 371281 فیلتر نتایج به سال:
We describe the design and testing of a new all-metal differential ebulliometer which is capable of working in the range 230 to 400 K at pressures to 3 MPa. It can be used to measure pure fluid vapor pressures and P ,T,x,y and infinite dilution activity coefficient data for binary mixtures. Tests for superheating and adjustments for condensed vapor holdup are described. Results are shown for pu...
Ionic liquids (IL) and hyperbranched polymers (HyP) represent new classes of nonvolatile selective solvents. By measuring vapor-liquid equilibria (VLE) of azeotropic and close boiling systems in the presence of ionic liquids or hyperbranched polymers, separation factors are derived and the potential of using IL and HyP as entrainer for extractive distillation is discussed. Exemplarily, the supe...
The Lattice-Boltzmann method has been seen as an alternative model for the computational simulation of fluid dynamics. It is based on the Boltzmann transport equation, which serves as the foundation of kinetic theory of gases. Considering its suitability for complex geometry problems, it has been widely applied for the description of fluid flow with one or more components inside porous media, e...
The phase diagram of a simple model with two patches of type A and ten patches of type B (2A10B) on the face centred cubic lattice has been calculated by simulations and theory. Assuming that there is no interaction between the B patches the behavior of the system can be described in terms of the ratio of the AB and AA interactions, r. Our results show that, similarly to what happens for relate...
In this paper, the solubility of CO2 in AMP solution have been measured at temperature range of ( 293, 303 ,313,323) K.The amine concentration ranges studied are (2.0, 2.8, and 3.4) M. A solubility apparatus was used to measure the solubility of CO2 in AMP solution on samples of flue gases from Thermal and Central Power Plants of Esfahan Steel Company. The modified Kent Eisenberg model was used...
Using continuum dynamic van der Waals theory in a radial 1D geometry with a Lennard-Jones fluid model, we investigate the nature of vapor bubble nucleation near a heated, nanoscale-curved convex interface. Vapor bubble nucleation and growth are observed for interfaces with sufficiently large radius of curvature while phase stabilization of a superheated fluid layer occurs at interfaces with sma...
• 3-Component Margules equation was used to predict vapor–liquid equilibria. Infinite dilution activity coefficients are the sole input for solvent pre-selection. Industrial cases were validate approach. Molecular solvents, ILs and DESs incorporated in screening. We present an easily accessible, open-access approach fast pre-selection of solvents extractive distillation at isobaric isothermal c...
A fast time-varying discharge model with safety system capabilities has been extended to handle the accidental release of multi-component mixtures. Previously the model could only handle pure components or “pseudo-component” mixtures, but the new multi-component model carries out vapour-liquid equilibrium (VLE) calculations. This allows accurate predictions of the phase envelope between a mixtu...
The size distributions and geometries of vapor clusters equilibrated with methanol-ethanol (Me-Et) liquid mixtures were recently studied by vacuum ultraviolet (VUV) laser time-of-flight (TOF) mass spectrometry and density functional theory (DFT) calculations (Liu, Y.; Consta, S.; Ogeer, F.; Shi, Y. J.; Lipson, R. H. Can. J. Chem. 2007, 85, 843-852). On the basis of the mass spectra recorded, it...
In this work is examined whether it is possible to predict solid-liquid-vapor phase equilibrium of ternary systems used in the SAS processing by the Peng-Robinson equation of state coupled with the LCVM mixing rules and the UNIFAC method for excess Gibbs free energy calculation. The enthalpy of fusion and the melting point temperature are estimated by group contribution methods. The results sho...
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