نتایج جستجو برای: trimetallic
تعداد نتایج: 256 فیلتر نتایج به سال:
Au nanorods have been extensively explored in various applications as the template for heterogeneous metallic nanostructures. However, Au bipyramids (AuBPs) have been paid much less attention although they possess an intriguing crystalline structure and extremely superior plasmonic properties which are absent in AuNRs. The state-of-the-art synthesis cannot produce pure AuBPs, which has become a...
The five novel compounds ALiM(BH4)4 (A = K or Rb; M = Mg or Mn) and K3Li2Mg2(BH4)9 crystallizing in the space groups Aba2 and P2/c, respectively, represent the first two-dimensional topologies amongst homoleptic borohydrides. The crystal structures have been solved, refined and characterized by synchrotron X-ray powder diffraction, neutron powder diffraction and solid-state DFT calculations. Mi...
Novel insights in the synthesis−structure−catalytic activity relationships of nanostructured trimetallic Pt−Rh−Sn electrocatalysts for the electrocatalytic oxidation of ethanol are reported. In particular, we identify a novel single-phase Rh-doped Pt−Sn Niggliite mineral phase as the source of catalytically active sites for ethanol oxidation; we discuss its morphology, composition, chemical sur...
We investigate the polarizability of trimetallic nitride endohedral fullerenes by partitioning the total polarizability into site specific components. This analysis indicates that the polarizability of the endohedral fullerene is essentially due to the outer fullerene cage and has insignificant contribution from the encapsulated unit. Thus, the outer fullerene cages effectively shield the encap...
We have rationally synthesized and optimized catalytic nanoparticles consisting of a gold core, covered by a palladium shell, onto which platinum clusters are deposited (Au@Pd@Pt NPs). The amount of Pt and Pd used is extremely small, yet they show unusually high activity for electrooxidation of formic acid. The optimized structure has only 2 atomic layers of Pd and a half-monolayer equivalent o...
Homoleptic metal-sugar complexes were obtained in the form of MnIIand FeII-diacetoneglucose derivatives. The protolysis of [Mn3Mes6] and [Fe2Mes4] (Mes ) 2,4,6-Me3C6H2) with DAGH (1,2:5,6-di-O-isopropylideneR-D-glucofuranose, diacetoneglucose) led to [M(DAG)2] [M ) Mn (1), Fe (2)]. Although monomeric in solution, they showed a different degree of aggregation in the solid state, iron being monom...
Electrolysis is one of the clean, environmentally friendly, and sustainable pathways to produce hydrogen for renewable energy storage. However, make electrolysis a competitive technology production, developing nonprecious metal-based catalysts oxygen evolution reaction (OER) mandatory. Several new classes electrocatalysts are developed with outstanding OER catalytic activity, stability, commerc...
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