نتایج جستجو برای: triaryl pyridine
تعداد نتایج: 13861 فیلتر نتایج به سال:
A high-yield one-pot two-step synthesis of 2-aminoimidazoles (2-AI), exploiting an under-air heterocyclodehydration process between α-chloroketones and guanidine derivatives, and using deep eutectic solvents (DESs) as nonconventional, "green" and "innocent" reaction media, has been accomplished successfully. The combination of either glycerol or urea with choline chloride (ChCl) proved to be ef...
Asymmetric preparation of all-carbon quaternary stereocenters is an important goal. Despite advances in formation of highly enantioenriched products with quaternary stereocenters proximal to a functional group, methods to install quaternary stereocenters isolated from functional groups are limited. Transition metal catalysis offers a potential solution, but prior cross couplings are limited to ...
A new series of fourteen dicationic flexible triaryl bis-guanidines 3a,b, bis-N-substituted guanidines 7a,b and 8a,b as well as bis-imidamides 9-12a,b having a 1,3- or 1,4-diphenoxybenzene scaffold backbone were synthesized. The in vitro activity of the novel dications as antiprotozoal agents against Trypanosoma brucei rhodesiense (T.b.r.) and Plasmodium falciparum (P.f.) was assessed. Interest...
IN THE TITLE COMPOUND (SYSTENATIC NAME: 3,4,5-trihy-droxy-benzoic acid pyridine monosolvate), C(5)H(5)N·C(7)H(6)O(5), the gallic acid mol-ecule is essentially planar (r.m.s deviation = 0.0766 Å for non-H atoms) and is linked to the pyridine mol-ecule by an O-H⋯N hydrogen bond. An intra-molecular O-H⋯O hydrogen bond occurs in the gallic acid mol-ecule. The gallic acid and pyridine mean planes ma...
Structure-activity relationships of the pyridine-pyrone moiety in pyripyropene A (1), a potent acyl-CoA: cholesterol acyltransferase (ACAT) inhibitor of fungal origin, were studied. Several kinds of aromatic or hetero ring substituents for the pyridine moiety were synthesized using unique degradation reaction, following by gamma-acylation. All the six synthesized analogs decreased the inhibitor...
LC-MS/MS method to determine hydrophobic N-alkyloxy substituted amidines: N-(2-ethylhexyloxy)pyridine-2-carboximidamide, N-(2-ethylhexyloxy)pyridine-3-carboximidamide, N-(2-ethylhexyloxy)pyridine-4-carboximidamide, N-decyloxy pyridine-2-carboximidamide, N-decyloxypyridine-3-carboximidamide and N-decyloxypyridine-4-carboximidamide was developed and validated in terms of linearity, precision and ...
Metal organic frameworks such as copper(II) monocarboxylate (formate and benzoate) pyridine derivatives and zinc(II) monocarboxylate (p-phenyl benzoate and benzoate) pyridine derivatives have been prepared. The complexes were synthesized at room temperature using pyridine or p-phenyl pyridine to grow single crystals, which were subsequently analyzed using single-crystal X-ray analysis. These st...
It has been shown previously that the diphosphopyridine nucleotidase from pig brain is capable of catalyzing an exchange reaction between various substituted pyridine compounds and diphosphopyridine nucleotide to form analogues of diphosphopyridine nucleotide (l-4). The variation in reactivity of the various analogues prepared in this manner indicates the importance of the grouping in position ...
The syn theses of diaquabis (3-hydroxyflavonato) cobalt (II) and bis(pyridine) bis (3hydroxyflavonato)cobalt(II) are described. Results from infrared spectra clearly show that the 3-hydroxyflavonato anion forms a chelate through the 3-hydroxy 4-keto groups. The electronic spectra of both complexes indicate that cobalt(II) has an octahedral geometry. Quantitative analyses of the isolated product...
In 1952, Korkes (1) reported that cell-free extracts of Clostri&urn kluyveri were capable of reducing pyridine nucleotides with hydrogen. Subsequent investigations have shown that a heatstable cofactor of undetermined nature present in boiled cell extracts was required (2). Pyridine nucleotide reduction with hydrogen has since been demonstrated in a number of other microorganisms (3-5). The pre...
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