The aim of the present study is to synthesize the oxovanadium complex of the V3+ ion with isatin sciff bases. Spectroscopic methods have been used to confirm these models of complexation and to understand the structures of the species formed in methanolic solution. We also have isolated a complex of Vanadium (III) with isatin schiff bases in the solid phase.

The response mechanism of the iron(III) chalcogenide glass membrane ion-selective electrode (ISE) in saline media has been studied using electrochemical impedance spectroscopy (EIS) and X-ray photoelectron spectroscopy (XPS). EIS equivalent circuits and XPS surface compositions for the FeIII ISE are consistent with the presence of two surface films probably comprising a outer surface layer (OSL...

Excited-state proton transfer in inclusion complexes of 1-aminopyrene and a-naphthol with cyclodextrins was studied by time-resolved spectroscopy. We find that the kinetic studies are much more sensitive to the complexation than are steady-state spectroscopic measurements. Our data suggest two distinct binding orientations for 1 -aminopyrene bound to 8-cyclodextrin. The rate of proton transfer ...

in this study the binding abilities of 1,3-calix[4]biscrown-6 (l) toward ba2+ and ca2+ have beenestablished in methanol by spectrophotometric measurements at 25±0.1 °c and 0.01 m ionicstrength, and with using specfit computer program; stability constants for 2 : 1, metal : ligandcomplexes has been estimated

in this research complexation of dioxovanadium(v) with nitrilotriacetic acid (nta) at differentionic strengths (0.1 to 1.0 mol dm-3) of sodium perchlorate as supporting electrolyte and ph rangeof 1.00-2.50 at 25 °c has been investigated by a combination of potentiometric and uvspectrophotometric measurements. stability constants of two species, v0211l- and vo2h2l havebeen calculated. ionic stre...

the present study was aimed at evaluating the possible use of inter polymer complexed (ipc) films of xanthan gum (xg) and cationic guar gum (cgg) for formulating domperidone bioadhesive films. formation of bonds between –coo¯ groups of xg and –n + (ch 3 ) 3 groups of cgg was evident in the ftir spectra of ipc films. bioadhesive strength of the films was evaluated employing texture analyser. wat...

The pattern of (13)C and (1)H nuclear magnetic resonance (NMR) shift changes produced by complexation of cobalt and nickel acetylacetonates with amines and alcohols indicates that there is more than one mode of operation of the contact interaction. A large effect with alternating signs is important at the alpha and beta carbons, but this effect seems to be overlaid by another influence that app...

Abst ra : The structure and complexation properties of macrocycles containing atoms from the second row of the periodic table (e.g., sulfur and phosphorus) have received less attention than the corresponding properties of macrocycles containing only first row atoms (e.g., oxygen and nitrogen). We describe results in two areas: macrocyclic thioethers for chelation of late transition metal ions, ...