A simple, microwave-assisted route for producing Au/Ag concentred sols by glucose reduction in water was developed. Ag-Au bimetallic nanoparticles stabilized by polyvinylpyrrolidone (PVP) were characterized and their catalytic activity was studied in the reduction of 4nitrophenol (4-NP) with NaBH4. Moreover they were tested as red ceramic inks for ink-jet printing technology. Since the research...

In the title compound, [{[(C6H5)3P]Ag}4{NCO}4], a distorted Ag4N4-heterocubane core is set up by four Ag(I) ions being coordinated by the N atoms of the cyanato anions in a μ 3-bridging mode. In addition, a tri-phenyl-phosphine ligand is datively bonded to each of the Ag(I) ions. Intra-molecular Ag⋯Ag distances as short as 3.133 (9) Å suggest the presence of argentophilic (d (10)⋯d (10)) inter-...

In this manuscript, we prepared gold nanorods (Au-NRs) through “silver-assisted seeded methodology” and studied their outermost layer using XPS spectroscopy ab initio calculations to compare the chemical states of constituents metallic core. Supporting first-principles employing a relativistic, full-potential all-electron method, with augmented plane waves plus local orbitals as basis set, ensu...

In the present study, 7% silver-low-density thin polyethylene films were successfully prepared through the melt mixing method. These films were applied to reduce the harmful antibacterial properties of Huso huso fillets at refrigeration temperatures, thus extending their shelf life. The total viable bacteria count for H. huso fillets wrapped in a 7% Ag/LDPE nanocomposite was 3.04±2.43 (log CFU/...

Introduction: The now extinct radionuclide Pd decays to Ag with a half life of 6.5Myr. Highly volatile element depleted (i.e. high Pd/Ag) Group IVA iron meteorites show good correlations between excess Ag and Pd/Ag. This strongly indicates the presence of live Pd at the start of the solar system [1]. Pd is both more refractory and more siderophile than Ag. Hence condensation/evaporation process...

background the physiological link between ghrelin and growth hormone (gh) has not yet been fully clarified. furthermore, the existence of a negative feedback mechanism between growth hormone–insulin-like growth factor (gh–igf)-i axis and ghrelin and the influence of amino acids on ghrelin secretion in children remain matters of debate. objectives to understand the regulation of ghrelin secretio...

Coupling seed-mediated co-reduction with galvanic replacement for the first time provides a route to trimetallic (Ag-Au-Pd) nanostructures with hollow interiors. Moreover, manipulating the synthetic conditions can suppress galvanic replacement and facilitate formation of trimetallic core@shell (Ag@Au-Pd) nanostructures. These results illustrate the role of seed composition in the synthesis of a...

A single Au nanoparticle (NP) with a diameter of 5 nm was transferred to the end of a Si-tip through a picking process, and an Ag shell with a controlled thickness was formed on the Au core. By carrying out tip-enhanced Raman scattering (TERS) measurements on biphenyl-4-thiol (BPT) with the Au@Ag NP-tip (overall diameter of 22-60 nm), we confirm that such tips show a plasmonic local-field enhan...

conclusions the study results indicated that the neonatal hbv immunization induced a long-term protection against hbv and was very efficacious in reducing chronic hbv infection rate in vaccinated young adults in iran. results anti-hbs seropositivity rate was detected in 224 of 510 [95% ci: 39-47] young adults. breakthrough infection (positive sera for anti-hbc without chronic infection) was obs...

The synthesis of tetranuclear gold complexes, a structurally unprecedented octanuclear complex with a planar [Au(I) 8 ] core, and pentanuclear [Au(I) 4 M(I) ] (M=Cu, Ag) complexes is presented. The linear [Au(I) 4 ] complex undergoes C-H functionalization of carbonyl compounds under mild reaction conditions. In addition, [Au(I) 4 Ag(I) ] catalyzes the carbonylation of primary amines to form ure...