The title compound, C13H14ClNO3, crystallizes with Z' = 2 in the space group Pca21, but a search for possible additional crystallographic symmetry found none. However, the crystal structure exhibits pseudosymmetry as the two independent mol-ecules are related by an approximate but non-crystallographic inversion located close to (0.38, 0.26, 1/2) in the selected asymmetric unit, and the structur...

A new tetra-dentate chiral Schiff base ligand, C(16)H(26)N(2)O(2), has been synthesized by the reaction of acetyl-acetone with (1R,2R)-(-)-1,2-diamino-cyclo-hexane. Both of the mol-ecules in the asymmetric unit are of the same chirality (R configuration), since the absolute configuration was determined by the starting reagent (1R,2R)-(-)-1,2-diamino-cyclo-hexane. The six-membered cyclo-hexane r...

introduction hemangioma is the most common benign tumor of the liver. most cases are asymptomatic and do not require treatment. a hemangioma can rarely be pedunculated; as a result, it may undergo torsion and infarction, which can make it symptomatic. case presentation we report the case of a 45-year-old woman with acute abdominal pain due to torsion of a giant pedunculated hepatic hemangioma a...

torsion of the gallbladder with gangrene is a rare condition which is generally due to an abnormal anatomical variation of the organ i.e., loss of fixation of the organ to the inferior margin of the liver and the presence of a long meso cyst. the case considered is a seven year old boy who presented with acute abdominal pain. he underwent laparotomy 36 hours after having sustained blunt abdomin...

Torsion of elastic and poroelastic circular shaft of radially inhomogeneous, cylindrically orthotropic materials is studied with emphasis on the end effects example for extruder. To examine the conjecture of Saint-Venant’s torsion, we consider torsion of circular shaft with one end fixed and the other end free on which tractions that results in a pure torque are prescribed arbitrarily over the fr...

We consider the Reidemeister torsion associated with SL2(C)representations of a knot group. A bifurcation point in the SL2(C)-character variety of a knot group is a character which is given by both an abelian SL2(C)representation and a non-abelian one. We show that there exist limits of the non-acyclic Reidemeister torsion at bifurcation points and the limits are expressed by using the derivati...

In this paper firt of all we introduce a generalization of torsion freeness of acts over monoids, called -torsion freeness. Then in section 1 of results we give some general properties and in sections 2, 3 and 4 we give a characterization of monoids for which this property of their right Rees factor, cyclic and acts in general  implies some other properties, respectively.

This paper deals with the problem of non-uniform torsion in thin-walled elastic beams with asymmetric cross-section, removing the basic concept of a fixed center of twist, necessary in the Vlasov’s and Benscoter’s theories to obtain a warping stress field equivalent to zero. In this new torsion/flexure theory, despite of the classical ones, the warping function will punctually satisfy the first...

The title compound, C(10)H(15)NO(2), crystallized with three mol-ecules in the asymmetric unit. These three mol-ecules are quite similar except for slight differences in the torsion angles of the substituents on the ring. The isopropyl C-C-N-C torsion angles (towards the carbon next to the ethyl bound carbon), for example, are -150.63 (11), -126.77 (13) and -138.76 (11)° for mol-ecules A, B and...