The effect of illumination on the viscosity of titania suspensions in silicone oil (insulating medium) and an aqueous buffer (conducting medium) was investigated. Commercially available P25 anatase titania was suspended at a volume fraction of 0.5%. A 12.3% increase in viscosity was observed when silicone oil suspension was used as the medium, while a 2.47% decrease in viscosity was observed fo...

Titania pillared montmorillonite from Indonesian montmorillonite by using titanium isopropoxide as precursor was successfully prepared. Physico-chemical character of material by using x-ray diffraction, gas sorption analyzer, diffuse reflectance UV-Visible, scanning electron microscope (SEM) and energy dispersive x-ray (EDAX) showed the dipersion of titania in dominantly anatase phase that is t...

The isothermal isotopic exchange reaction of O2 with 16O of chromium(VI) oxide supported on zirconia, alumina, and titania has been investigated with in situ laser Raman spectroscopy. The isotopic exchange reaction is dependent on the support type, the Cr loading, and the reaction temperature. Complete isotopic exchange of chromium(VI) oxide with O2 is difficult to achieve and requires several ...

the gas separation performance of commercial ceramic titania and hybrid silica (hybsi®) membranes was assessed using the gas permeation and permporometry methods. results indicated that the hybsi® membranes have a hybrid surface containing regions covered by a polymeric matrix and others with inorganic pores. these membranes have high h2 selectivity, which increases significantly with temperatu...

the nanostructured anatase tio2 with high thermal stability was prepared by polymeric sol-gel method without any additives. the particle size distribution of polymeric titania sol was determined by dynamic light scattering (dls). then properties of obtained titania were investigated by tg-dta, xrd, fesem and tem. also, the decolorization capability of resultant anatase was evaluated using methy...

the preparation of nano-sized tio2 by titanium tetraisopropoxide (ti(oipr)4) via sol-gelmethod using acid as a catalyst is investigated and the optimized conditions concerning theproportional amount of acid, water, alcohol is established by xrd and sem. the effect ofcalcination temperature on phase transformation of tio2 (rutile, anatase and brookite) wasdetermined by xrd. the smallest grain si...

Cell-assemblies with different cell shapes were used as macrotemplates in the bioinspired synthesis of hierarchical macro-mesoporous titania with tunable macroporous morphology and enhanced photocatalytic performance.

A successful synthetic tissue engineering scaffold requires a hierarchical internal structure with interconnecting pores for nutrition transportation, cell infiltration and vascularization as well as nanoscale surface features favorable for cell attachment and long-term functions. However, traditionally, fabricating macro-scale scaffolds in a defined manner from nano-scale constituents has prov...

Titania coated magnetic hollow mesoporous silica spheres with high surface area were created, which can be used in efficient and rapid capture of phosphopeptides from peptide mixtures.