Bulk metallic Au is chemically inert and catalytically inactive as a consequence of combination of valence d orbitals and diffused valence s and p orbitals. Recently, Au nanoparticles have been found to be catalytically active when supported on metal oxides such as TiO2, SiO2, Fe2O3, Co3O4, NiO, Al2O3, MgO, etc. 1 6 For example, Au nanoparticles supported on a TiO2(110) surface demonstrate cata...

The aim of this research was to prepare rare metal (Er, Yb)-modified TiO2 nanoparticles by a sol-gel method. The obtained nanoparticles were characterized by BET measurements, UV-Vis spectra and the Laser-induced fluorescence (LIF) method. Visible light photocatalytic activity of the sample was studied by photodegradation of phenol while considering the influence of the dopant concentration. Th...

Densely stacked Ag nanoparticles with an average diameter of 199 nm were effectively deposited on TiO2-coated cicada wings (Ag/TiO2-coated wings) from a water-ethanol solution of AgNO3 using ultraviolet light irradiation at room temperature. It was seen that the surfaces of bare cicada wings contained nanopillar array structures. In the optical absorption spectra of the Ag/TiO2-coated wings, th...

Carbon coated TiO2 (TiO2@C) is fabricated by a convenient and green one-pot solvothermal method, in which ethylene glycol serve as both the reaction medium and carbon source without the addition of any other carbon additives. During the solvothermal process, ethylene glycol polymerize and coordinate with Ti4+ to form the polymeric ligand precursor, then the polymer brushes carbonize and convert...

Immobilization of cellulase from Aspergillus niger on TiO2 nanoparticles was studied by two different approaches--physical adsorption and covalent coupling. A. niger was selected, as it is generally non-pathogenic, is found in nature in the broad range of habitats and produces cellulase extracellulary. For covalent method, TiO2 nanoparticles were modified with aminopropyltriethoxysilane (APTS)....

The focus of this work is on composite materials of inorganic nanoparticles such as TiO2 embedded within microspheres of a responsive polymeric network. Microgels of N-isopropylacrylamide (NIPAM) with interpenetrating (IP) linear chains of poly(acrylic acid) (PAAc) were synthesized to promote the incorporation of TiO2. Dynamic light scattering measurements of the IP-microgels in aqueous environ...

BACKGROUND Poor mechanical properties are among the main limitations of acrylic resins. Addition of titanium dioxide (TiO2) nanoparticles to acrylic resin has been shown to improve its mechanical properties with an adverse effect on its color. Thus, this study sought to assess the tensile and impact strength of a color modified heat cure acrylic resin reinforced with TiO2 nanoparticles. MATER...

Ag-TiO2@polyethylene glycol (PEG) nanoparticles were continuously obtained in a single-pass configuration by appropriately reacting freshly flame-synthesized TiO2 with Ag formed in an ultrasonic aqueous medium containing PEG. When the proposed synthesis was kept constant, the production rate for Ag-TiO2@PEG nanoparticles reached approximately 3 g/h while only using a combination of a lab-scale ...

Au, Cu and bimetallic Au-Cu nanoparticles were synthesized on the surface of commercial TiO2 compounds (P25) by reduction of the metal precursors with tetrakis (hydroxymethyl) phosphonium chloride (THPC) (0.5 % in weight). The alloyed structure of Au-Cu NPs was confirmed by HAADF-STEM, EDS, HRTEM and XPS techniques. The photocatalytic properties of the modified TiO2 have been studied for phenol...