Riboswitches are non-coding elements upstream or downstream of mRNAs that, upon binding of a specific ligand, regulate transcription and/or translation initiation in bacteria, or alternative splicing in plants and fungi. We have studied thiamine pyrophosphate (TPP) riboswitches regulating translation of thiM operon and transcription and translation of thiC operon in E. coli, and that of THIC in...

While it is evident that a metal ion in aqueous solution interacts electrostatically with water molecules and the anions present in the solution, it is equally apparent that often the metal ion chemically combines with varying numbers of ions or molecules to form complex species. This tendency towards coordination complexing is observed most often with the transition metals and results in a ser...

A mathematical model for the free radical polymerization of styrene is developed to predict the steady-state and dynamic behavior of a continuous process. Special emphasis is given for the kinetic and thermodynamic models, where the most sensitive parameters were estimated using data from an industrial plant. The thermodynamic model is based on a cubic equation of state and a mixing rule applie...

The entropy S is a dimensionless quant i ty since the tempera ture T has dimensions of energy so that it can be measured in energy units. The r a n d o m variable n is the number of particles, and n s denotes its average or mos t probable value. E is the internal energy, p the chemical potential and V the volume. According to (1), the entropy is the thermodynamic potential tha t determines the ...

Stabilization of enzymes has become a major focus in the quest to improve the activity, sustainability and recyclability of enzymes for their successful integration into both industry and medicine. Here, we describe the kinetic and thermodynamic stabilization of a variety of enzymes in the presence of cationic multifunctional polymeric nanoparticles.

Work during 1963 is reported and the work from mid-1960 reviewed on a comprehensive program of thermodynamic and kinetic studies necessary to the theoretical consideration to temperatures of 3000K of the reactions of the zirconium and hafnium carbides and borides with oxygenor halogen-containing atmospheres. ; • Work presented includes: preparation of borides and carbides; low ', temperature he...