in recent years many research works have been carried out on anti-corrosive nanocomposites coatings containing mineral reinforcements. the most important criteria in these attempts are polymerization method and the type of matrix and reinforcement of nanocomposites. in this regard, the physical and mechanical properties of the polymers in which a small amount of filler is used can be improved. ...

The buckling torque may be much less than the yield torque in very thin rectangular tubes under torsion. In this paper, simple closed-form formulae are presented for buckling analysis of long hollow rectangular tubes under torsion. By the presented formulae, one can obtain the critical torque or the critical angle of twist of the tube in terms of its geometrical parameters and material constant...

-Clay-modified electrode research indicates that adsorbed complexes are electroactive if the adsorption sites are clay edges. Interlayer adsorbed complexes may be electroactive ifa charge shuttle is added or if interlayer swelling is large. Conductivity of the film towards anionic species depends upon the swelling of the clay, which depends on the electrolyte concentration and speciation. The d...

SUPERCRITICAL CARBON DIOXIDE PROCESSING OF NANO CLAYS ANDPOLYMER/CLAY NANOCOMPOSITESbyMIHAI MANITIUAugust 2010Advisor: Rangaramanujam KannanCo-Advisor: Esin GulariMajor: Chemical EngineeringDegree: Doctor of Philosophy Effective dispersion of the fillers in a polymer matrix and improvement of polymer clayinteractions are two key challenges in the field of...

The segmental dynamics of rigid, intermediate, and mobile molecular components in carboxyl terminated polybutadiene (CTPB)/ organo−clay (C18−clay) systems was characterized by fully refocused H NMR FID. In addition, H DQ NMR experiments allowed semiquantitative monitoring of changes in segmental dynamics near the interface. Both methods suggest a critical concentration of 60 wt % CTPB, indicati...

Predicting soil phosphorus (P) needs and P fertilizer requirements is important for plant nutrition and reducing environmental risk. The P requirement (PR) can be calculated from three components: the current status of soil P (P0), soil P buffer coefficient (PBC), and the soil P critical level (PCL). The PBC and PCL can be predicted from soil clay content using linear-plateau models. The PR, PB...

Magnetic hollow spheres with a controlled diameter and shell thickness have emerged as an important class of magnetic nanomaterials. The confined hollow geometry and pronouncedly curved surfaces induce unique physical properties different from those of flat thin films and solid counterparts. In this paper, we focus on recent progress on submicron-size spherical hollow magnets (e.g., cobaltand i...

Preparation of a novel organically modified clay from spent oil base drilling mud (SOBM) that could serve as core-shell clay filler for polymers is herein reported. Due to the hydrophilic nature of clay, its compatibility with polymer matrix was made possible through modification of the surface of the core clay sample with 3-aminopropyltriethoxysilane (3-APTES) compound prior to its use. Fourie...

Plasma generation over large areas using a hollow cathode discharge is described in this study. Radio frequency linear hollow cathodes in several arrangements, for operation at reduced gas pressure and suitable for scale-up, are presented. Examples of surface processing and coating by PVD, both by hollow cathode discharge (HCD) and hollow cathode arc (HCA), are given. A non-equilibrium atmosphe...

Clay minerals are considered the most important components of clastic reservoir rock evaluation studies. The Shurijeh gas reservoir Formation, represented by shaly sandstones of the Late Jurassic-Early Cretaceous age, is the main reservoir rock in the Eastern Kopet-Dagh sedimentary Basin, NE Iran. In this study, X-ray diffraction (XRD), X-ray fluorescence (XRF), scanning electron microscopic (S...