In this study, we showed for the first time that barium (Ba) codoping improves luminescent properties of terbium (Tb)-doped SiO2 nanoparticles (NPs). particular, quantum yield (QY) SiO2-Ba,Tb NPs was found to be ∼10.7%, whereas QY bare SiO2-Tb only ∼4.3%. Several mechanisms luminescence enhancement have been proposed. We strongly believe methodology can used create alternative silica-based with...

Two different charge carrier trapping processes have been investigated in RE2O2S:Ln3+ (RE = La, Gd, Y, and Lu; Ln = Ce, Pr, and Tb) and RE2O2S:M (M = Ti4+ and Eu3+). Cerium, praseodymium and terbium act as recombination centers and hole trapping centers while host intrinsic defects provide the electron trap. The captured electrons released from the intrinsic defects recombine at Ce4+, Pr4+, or ...

Aptamers, single-stranded nucleic acids that can selectively bind to various target molecules, have been widely used for constructing biosensors. A major challenge in this field, however, is direct sensing of analytes in complex biological media such as undiluted serum. While progress has been made in developing an inhomogeneous assay by using a preseparation step to wash away the interferences...

An emissive terbium complex has been conjugated to a C12 chain, Lys-Arg7, Arg7, a tetraguanidinium cation and human serum albumin; two-photon excitation at 720 nm facilitated microscopy studies revealing cell localisation profiles with the oligo-guanidinium conjugate localising in mitochondria but causing apoptotic cell death (IC(50)12 microM), the C12-amide complex giving rise to necrotic cell...

We report on our progress towards the integration of nonreciprocal optical elements in, for example, an integrated optical waveguide isolator on conventional semiconductor photonic platforms. Our approach uses an evanescent interaction with a magneto-optic iron garnet upper cladding. Specifically, ceriumand bismuthsubstituted yttrium and terbium iron garnets were investigated. Device fabricatio...

Aluminium terbium alloys were prepared by simultaneous thermal evaporation resulting in a thin film library covering a 5 to 25 at.% Tb compositional spread. Synchrotron x-ray diffraction (XRD) proves all of the alloys to be amorphous. Scanning electron microscopy (SEM) measurements reveal the structural changes upon increase in Tb content with the formation of small, Tb-rich segregations right ...