The peng-Robinson (PR), a cubic equation of state (EoS), is extended to polymers by using a single set of energy (A1, A2, A3) and co-volume (b) parameters per polymer fitted to experimental volume data. Excellent results for the volumetric behavior of the 11 polymer up to 2000 bar pressure are obtained. The EoS is applied to the correlation and prediction of Henry constants in polymer solutions...

We present the development of a high-pressure apparatus for measurements of diffusion coefficients in supercritical fluids. The Taylor dispersion method has been adapted to conduct experiments at the pressures up to 25.0 MPa. In order to test the developed set-up, binary diffusion coefficients D at infinite dilution in supercritical carbon dioxide have been measured for a reference system, benz...

We present a theory for the temperature and density dependence of the vibrational lifetime T1 and the vibrational line position n of a solute in a supercritical solvent, both close to and far from the critical point. The theory is based on the relation between a classical force correlation function and T1 and n. The force correlation function is determined from density functional theory, and ca...

This study investigates the heat transfer in a simple pure fluid whose temperature is slightly above its critical temperature. We propose an efficient numerical method to predict the heat transfer in such fluids when the gravity can be neglected. The method, based on a simplified thermodynamic approach, is compared with direct numerical simulations of the Navier-Stokes and energy equations perf...