Future modifications of fuels should include evaluation of the proposed constituents for their potential to damage environmental resources such as the subsurface environment. Batch and column experiments were designed to simulate biofuel spills in the subsurface environment and to evaluate the sorption and desorption behavior of target fuel constituents (i.e., monoaromatic and polyaromatic hydr...

HYPOTHESIS Phosphate influences the sorption of metals to iron (hydr)oxides. An enhanced formation of inner-sphere complexes on the (hydr)oxide surface can be attributed to electrostatic interactions and/or to changes in metal coordination on the iron (hydr)oxide surface. Phosphate was expected to increase cadmium(II) sorption on ferrihydrite. It should be possible to identify changes in cadmiu...

The paper outlines the concept of process intensification and integration, with a particular focus on sorption-enhanced, solid-catalyzed chemical processes. An alternative attractive solution to system parallel fixed-bed apparatuses is evaluated, which utilizes solids’ circulation in dual fluidized-bed reactor–regenerator system. This allows for continuous mode operation greatly simplifies cont...

Metal-organic frameworks are a class of crystalline porous materials with potential applications in catalysis, gas separation and storage, and so on. Of great importance is the development of innovative synthetic strategies to optimize porosity, composition and functionality to target specific applications. Here we show a platform for the development of metal-organic materials and control of th...

A bis(phosphonatemonoester) is employed as a linker in a Zn(II) metal organic framework. The complex is a layered structure pillared only by vdW interactions between alkyl groups. Nonetheless, permanent pores are formed as confirmed by PXRD and gas sorption analysis.

A new Pb(II) imprinted mercapto functionalized Montmorillonite was synthesize by an easy one step reaction by combining a surface imprinting technique for selective phase extraction of Pb(II) prior to its determinations by flame atomic absorption spectroscopy. The modified sorbent was characterized by FTIR and studied for preconcentration and determination of Pb(II) in natural water samples. Th...

• Biochar and digestate were tested as novel sorbents for biopurification systems. • Digestate and biochar mixture enhanced the sorption coefficient by a factor of N50. • Boscalid and pyrimethanil exhibited N25 fold higher Kd/Koc values than bentazone. • Desorption was hysteretic (H ≥ 0.001) for biochar and digestate based soil

A novel porous organic polymer has been synthesized using the molecular building block approach to deliberately encompass aldehyde functionalities amenable to post functionalization. The resultant porous framework allows a facile, one-step quantitative and post-synthetic functionalization by amines, permitting enhanced CO2 sorption properties.

A 1-D heterogeneous model of sorption-enhanced steam methane reforming (SE-SMR) process in a packed bed reactor consisting nickel catalyst well mixed with CO2 sorbent particles is investigated for three types common sorbents. The performance SE-SMR studied under low medium pressure conditions (3 – 11 bar) to find the optimum operating conditions. Optimal CaO sorption corresponding 82% CH4 conve...

We model a novel industrial blue hydrogen production process, the sorption enhanced autothermal membrane (ISEAM) with potential to produce constant fuel cell grade 99.99% purity, regardless of upstream process upsets