In the present work we report the results obtained with a methodology based on direct coupling of a headspace generator to a mass spectrometer for the identification of different types of petroleum crudes in polluted soils. With no prior treatment, the samples are subjected to the headspace generation process and the volatiles generated are introduced directly into the mass spectrometer, thereb...

A comprehensive study was conducted to determine thorium, uranium and potassium elemental concentrations in surface soils throughout the accessible area of Cyprus using high-resolution gamma-ray spectrometry. A total of 115 soil samples was collected from all over the bedrock surface of the island based on the different lithological units of the study area. The soil samples were air-dried, siev...

Nitrogen leaching from boreal and temporal forests, where normally most of the nitrogen is retained, has the potential to increase acidification of soil and water and eutrophication of the Baltic Sea. In parts of Sweden, where the nitrogen deposition has been intermediate to high during recent decades, there are indications that the soils are close to nitrogen saturation. In this study, four di...

The effect of incorporation of Si02 on the behavior of a TiO2-based photocatalyst prepared by a sol-gel technique from organometallic precursors is described. Application of photocatalysts with different TiOd Si02 ratios to the photodecomposition of rhodamine-6G (R-6G) demonstrates that a ratio of 30/70 produces a catalyst about 3 times more active than Degussa P-25 TiO2. Larger amounts of Si02...

Red maple (Acer rubum), a common deciduous tree species in Northern Ontario, has shown resistance to soil metal contamination. Previous reports have indicated that this plant does not accumulate metals in its tissue. However, low level of nickel and copper corresponding to the bioavailable levels in contaminated soils in Northern Ontario causes severe physiological damages. No differentiation b...

Failure of the quay walls due to earthquakes results in severe economic loss. Because of hazards threatening such inexpensive nodes of national and international transportation networks, seismic design of quay walls is still an evolving topic in marine structural engineering. This study investigates the sensitivity of the gravity-type quay wall stability respect to uncertain soil and seismic pr...

We report lead isotopic ratios and concentrations from a basaltic soil chronosequence in Hawaii. Substrate ages at the sites range from 300 years to 4.1 million years. All soils show a net addition of Pb above the contributions made by basaltic weathering, indicating that atmospheric deposition of natural or pollutant sources is important across the sequence. Isotopic ratios from the chronoseqe...

The amendment of soil with biochar has been demonstrated to have an effect not only on the soil physicochemical properties, but also on soil microbial community composition and activity. Previous reports have demonstrated significant impacts on soil microbial community structure. These impacts are modulated not only by the biochar composition, but also on the soil’s physicochemical characterist...

Can a climate-triggered export of old contaminants from the soil alter the lead (Pb) contaminant burden of subarctic lakes? To address this question, we reconstructed the pollution history of three high latitude lakes situated in a region where a recent climatic shift has occurred. Dated sediment records were used as archives of past Pb inputs to the lakes, where the difference in the (206)Pb/(...