Reaction of 3,4,5,6-tetrahydro-2-pyrimidinethiol, prepared by cyclocondensation reaction of 1,3-diamino propane 1 and carbon disulfide, with ethyl chloroacetate and substituted aromatic aldehydes in the presence of sodium acetate and acetic acid gave 2-[(Z)-1-(aryl)]-6,7-dihydro-2H-isothiazolo[2,3-a]pyrimidine-3(5H)-one derivatives 3(a-j) in good yields. 1H-NMR spectroscopy, and elemental analy...

A simple and mild procedure for the conversion of anilines into aryl isocyanates is described using the 3-hydroxypropylammonium acetate (HPAA) ionic liquid as a novel and efficient media has been explored in the synthesis of aryl isocyanates from the reaction of substituted urea with sodium nitrite in a water immiscible solvent. This ionic liquid can be easily recovered and reused for many time...

McCrudden’s (1, 2) method has come to be recognized as the best for the accurate determination of calcium. The method is to precipitate the calcium as oxalate in the presence of sufficient ammonium chloride to hold the magnesium oxalate in solution, and of sufficient acid to hold the calcium oxalate partly in solution. Sodium acetate is then added to decrease the acidity and to precipitate the ...

mg(oh)2 nanoparticles were synthesized by a rapid microwave reaction. the effect of sodium dodecyl sulfonate (sds as anionic surfactant) and cetyl tri-methyl ammonium bromide (ctab as cationic surfactant) on the morphology of magnesium hydroxide nanostructures was investigated. multi wall carbon nano tubes was organo-modified for better dispersion in cellulose acetate matrix. the influence of m...

the objective of the present study was to compare the impact of ovsynch and progesterone-based ovulation synchronization protocol on ovarian response and conception in buffalo (n=19) exhibiting subestrus during low-breeding season (maximum ambient temperatures and relative humidity ranging from 36-45°c and 30-80%, respectively). group i buffalo (n=10) were administered ovsynch protocol (d 0 and...

Most methods for the colorimetric estimation of sodium depend upon the precipitation of the metal as sodium zinc uranyl acetate, a reaction first proposed by Barber and Kolthoff (1928). The precipitated salt, after washing, is treated in various ways to give coloured solutions. There are thus three distinct stages which have to be considered in the estimation: (1) precipitation, (2) washing of ...

Streptomyces chartreusis NRRL 3881 produces the divalent cation ionophore antibiotic A231871). This antibiotic is primarily active against Grampositive bacteria and fungi and has been used extensively to investigate the role of divalent cations in regulating cellular physiological processes2,3,4). The chemical structure of A231875.6) indicates that it is a member of a new class of ionophorous a...

Electro-active elemental sulphur dissolved in hydrazine hydrate solvent was studied by d.c. polarography, cyclic voltammetry and millicoulometry in sodium acetate, ammonium tartrate and sodium phosphate buffers in an aqueous medium. The method, which uses a mercury electrode, is highly sensitive with less interference than other polarographic methods. The method was extended to the determinatio...

Cadmium sulfide nanoparticles were grown using wet chemical method by dissolving the reactants of cadmium acetate and sodium sulfide in the presence of thioglycerol (TG) as capping agent in ethanol solvent. Different nanoparticle sizes and size distribution were obtained through varying the molarities of thioglycerol. At higher TG concentration, synthesis provides a nearly monodisperse nanopart...

The ultrasonic velocity (U), density ( ρ) and viscosity (η) measurements have been carried out for four amino acids namely L-alanine, L-leucine, L-valine and L-proline in aqueous sodium acetate solution as a function of composition at 303, 308 and 313K. Experimental data have been used to estimate the adiabatic compressibility (β), change in adiabatic compressibility (∆β), relative change in ad...