X-ray diffraction from crystal surfaces at grazing angles gives rise to X-ray standing waves above and below the surface. Expressions are derived for the fluorescence observed from atoms located on or in a crystal as a result of excitation by the grazing-angle X-ray standing waves. In addition to the dependence of the fluorescence on the position of the atom with regard to the crystal plane tha...

Single crystals of pure and picric acid doped thiourea were grown by slow evaporation technique. Single crystal structure was determined by X-ray diffraction data and it reveals that the crystal belongs to orthorhombic crystal system with space group of Pnma. The dielectric constant and dielectric loss were calculated by varying frequencies at different temperatureThemicrohardness test reveals ...

The technique of coherent X-ray diffraction imaging (CXDI) has recently shown great promise for the study of inorganic nanocrystals. In this work the CXDI method has been applied to the study of micrometer-size protein crystals. Finely sampled diffraction patterns of single crystals were measured and iterative phase-retrieval algorithms were used to reconstruct the two-dimensional shape of the ...

Nonlinear optical single crystals of ammonium pentaborate (APB) were grown by the slow cooling method from aqueous solution. Grown crystal was characterized by powder X-ray diffraction (PXRD) and FT-IR spectral analysis. Perfection of the grown crystal was evaluated by high-resolution X-ray diffractometry (HRXRD). The effect of nylon threading on the perfection of the grown bigger crystal was a...

The molecular structure of esomeprazole magnesium derivative in the solid-state is reported for the first time, along with a simplified crystallization pathway. The structure was determined using the single crystal X-ray diffraction technique to reveal the bonding relationships between esomeprazole heteroatoms and magnesium. The esomeprazole crystallization process was carried out in 1-butanol ...

In current study, nanoparticles and single crystals of a Zn(II) coordination complex, [Zn(dmph)I2](1), {dmph=2,9-dimethyl-1,10-phenanthroline(neocuproine)}, have been synthesized by the reaction of zinc(II) acetate, KI and neocuproine as ligand in methanol using sonochemical and heat gradient methods, respectively. The nanostructure of 1 was characte...

X-ray diffraction topography provides a simple, fast, and direct technique for imaging crystal disorder. In conventional single-crystal diffraction (e.g., as performed by macromolecular crystallographers), the sample is illuminated using a beam with a finite angular divergence and the diffraction pattern is recorded using a detector placed ~0.11.0 m from the sample. Under these conditions, the ...

Structure-activity relationships in heterogeneous catalysis are challenging to be measured on a single-particle level. For the first time, one X-ray beam is used to determine the crystallographic structure and reactivity of a single zeolite crystal. The method generates μm-resolved X-ray diffraction (μ-XRD) and X-ray excited optical fluorescence (μ-XEOF) maps of the crystallinity and Brønsted r...

New Schiff-base compound (E)-4-methoxy-N-(4-hydroxybenzylidene) aniline has been synthesized from the reaction of 4-hydroxybenzaldehyde with 4-methoxyaniline in methanol at 50ºC, and has been characterized by using elemental analysis and FT-IR spectroscopy. The crystal structure of the title compound has been determined by single crystal X-ray diffraction study. The title compound crystallizes ...