statement of problem: ceramics as in ceramo-metallic and all ceramic tooth restorations have grown popular owing to their high tissue compatibility and esthetic advantages. such restorations have the capability to deliver valuable services over a long period of time; however, failures under intraoral conditions are not unanticipated. purpose: the purpose of this in-vitro study was to investigat...

It is often desirable to sequester cells in specific locations on the surface and to integrate sensing elements next to the cells. In the present study, surfaces were fabricated so as to position cytokine sensing domains inside non-fouling poly(ethylene glycol) (PEG) hydrogel microwells. Our aim was to increase sensitivity of micropatterned cytokine immunoassays through covalent attachment of b...

OBJECTIVES Five commercial dental silanes were evaluated in vitro as adhesion promoters bonding a luting cement to silica-coated titanium surfaces. METHODS Titanium slides (n=20) were cleaned with alumina sand and then silica-coated with a special sand consisting of alumina particles coated with silica. The bonding of a resin composite cement (3M ESPE, Seefeld, Germany) to silica-coated and s...

In the title mol-ecule, C(22)H(24)OSi, the Si-O-C angle is 139.79 (11)°, the O-C-C angles of the triphenyl-meth-oxy group are in the range 106.13 (13)-109.22 (14)° and the O-Si-C angles of the trimethyl-sil-yloxy group are in the range 103.08 (10)-113.53 (10)°. In the crystal, face-to-face π-π interactions are observed between the phenyl rings [centroid separation = 4.194 (1) Å, interplanar spa...

This study focuses on the preparation of Ni-plated polystyrene (PS) microspheres (diameter 3.7–4.5 μm). These Ni-plated PS microspheres have core–shell structures that were designed and prepared using an organic polymer core (PS with 3-(trimethoxysilyl) propyl methacrylate (TSPM)) and an inorganic metal (Ni) plated shell. The polymer microspheres were synthesized by dispersion copolymerization,...

The performance and service life of glass-or ceramic-filled polymeric composites depend on the nature of their resin, filler and interfacial phases as well as the efficacy of the polymerization process. The synergy that exists between the organic polymer matrix and the usually inorganic reinforcing filler phase is principally mediated by the interfacial/interphasial phase. This latter phase dev...

Introduction: The rehabilitation of teeth by means of ceramic indirect restorations has been widely performed. Previous studies has shown the effectiveness of silane coupling agents on improving the bond strength of the adhesion of resin cements to ceramics; however, some studies question the use of silane. Objective: To evaluate the effect of silane application on the microtensile bond strengt...

We have determined the crystal structures of two deca-chloro-cyclo-penta-silanes, namely bis-(tetra-n-butyl-ammonium) dichloride deca-chloro-cyclo-penta-silane di-chloro-methane disolvate, 2C16H36N+·2Cl-·Si5Cl10·2CH2Cl2, (I), and bis-(tetra-ethyl-ammonium) dichloride deca-chloro-cyclo-penta-silane di-chloro-methane disolvate, 2C8H20N+·2Cl-·Si5Cl10·2CH2Cl2, (II), both of which crystallize with d...

Background and objectives : The fracture of acrylic maxillary complete dentures is a commonly seen clinical problem which usually occurs due to heavy occlusal forces or accidental damage.The objectives of the study were to measure the impact strength of maxillary complete dentures fabricated with high impact acrylic resin and to evaluate the effect of woven E-glass fiber and silane treated glas...