The high yield electrophilic substitution procedure for the synthesis of bis indolyl methanes at room temperature has been carried out effectively by using a novel metal supported organo catalyst. advantages this method include simple conditions, great yields, less work-up, an environmentally friendly process and reusable solid Several were synthesised confirmed IR, H1 13C NMR techniques. Catal...

The reaction of CH3O2 radicals with acetaldehyde on the solid surface of NH4NO3 has been studied in a flow capillary reactor at low pressure and room temperature. The experiments were performed using EPR spectrometer combined with the kinetic method of radicals freezing. Peroxy radicals revealed an oscillation complex behavior during the process regarding to the phenomenon of radicals multiplic...

The properties of CaCu3.1Ti4O12.1 [CC3.1TO] ceramics with the addition of Al2O3 nanoparticles, prepared via a solid-state reaction technique, were investigated. The nanoparticle additive was found to inhibit grain growth with the average grain size decreasing from approximately 7.5 μm for CC3.1TO to approximately 2.0 μm for the unmodified samples, while the Knoop hardness value was found to imp...

Three new Schiff bases derived from the condensation reaction of thiophene-2-carbaldehyde and DL-alanine, DL-valine and DL-phenylalanine have been synthesized and their Co(II), Ni(II) and Cu(II) complexes have been prepared. The Schiff bases and the complexes have been characterized by their analytical and spectral data. The protonation constants of the Schiff bases and stability constants of t...

In this work, thin film yttria-stabilized zirconia [YSZ] solid electrolytes were sputtered onto insulating substrates at room temperature and 600oC in order to produce different average grain sizes (~15-50 nm). For reference, polished samples of single crystal and bulk, poly-crystalline YSZ were also used. Platinum film electrodes were then sputtered on top and lithographically patterned to giv...

The title compound, 1-phenyl-3,3-di(1H-pyrazol-1-yl)propan-1-one, was synthesized in a 52% yield for the first time by one-step reaction between 1H-pyrazole and 1-phenylprop-2-yn-1-one (their ratio being 2:1) solid Al2O3 at room temperature. product characterized 1H-NMR, 13C-NMR, IR spectroscopy, X-Ray diffraction elemental analysis.

nano-sized batio3 powders with particular nb concentrations were prepared by rotary- hydrothermal (rh) method. hydrothermal method was used at 180 °c for 5 hours with new ti pressure and the teflon vessel was rotated at a speed of 160 rpm during the hydrothermal reaction. new hydrothermal method was used instead of previous solid state reaction for the system batio3±nb2o3 in high temperature to...

Dynamic Nuclear Polarization solid-state NMR holds the potential to enable a dramatic increase in sensitivity by exploiting the large magnetic moment of the electron. However, applications to biological solids are hampered in uniformly isotopically enriched biomacromolecules due to line broadening which yields a limited spectral resolution at cryogenic temperatures. We show here that high magne...

The role of dietary fats and oils in human nutrition is one of the most important areas of concern and investigation in the field of nutritional science. The findings of investigations on this subject have wide-ranging implications for consumers, health-care providers and nutrition educators as well as food producers, processors and distributors. New evidence concerning the benefits and risks a...

The role of dietary fats and oils in human nutrition is one of the most important areas of concern and investigation in the field of nutritional science. The findings of investigations on this subject have wide-ranging implications for consumers, health-care providers and nutrition educators as well as food producers, processors and distributors. New evidence concerning the benefits and risks a...