The reactions of aqueous H2MoO4 at low pH with titanium(II), titanium(III), europium(II), vanadium(II), and germanium(II), as monitored at 430 nm, give biphasic profiles featuring a sharp rise in absorbance followed by a marked decrease (Fig. 1). The final product is the dimeric Mo(V) cation, [Mo2O4]2+, and the strongly absorbing intermediate is taken as a monomeric Mo(V) species. The molar abs...

The reaction of various [Os(L)(2)(L')](2+) complexes (where L and L' are phenanthroline, diphosphine or diarsine ligands) and organic reducing agents after chemical or electrochemical oxidation of the reactants produces an emission of light corresponding to MLCT transitions. In certain instances, the emission was greater than that of [Ru(bipy)(3)](2+), but the relative signals were dependent on...

LTHOUGH many substances have been shown to increase iron ahsorption, the mechanism of this action is obscure. Fructose, for example, increases iron absorption in rats, and it has been suggested that its effect depends on its ability to chelate iron.4 We proposed to test this hypothesis, and to in ’estiga e possible relationships between the effects of various metabolic substrates and reducing a...

Aqueous based controlled decoration of platinum nanoparticles on plasma treated carbon nano-onions (CNOs) occurs within the shear flow generated by a vortex fluidic device (VFD), using ascorbic acid as the reducing agent, with the electrocatalytic potential of the resulting Pt-NPs@CNOs nano-composites demonstrated.

Phosphomolybdate has been employed simultaneously as the oxidizing agent for the monomer polymerization and the reduced polyoxometalate is used as reducing agent for the reduction of metal ions. The composites thus obtained have been characterized and may have many potential applications.

A one-pot sonochemical reaction of Cu(NO3)2 with glutathione (GSH), the latter functioning as a reducing agent and a stabilizing agent, rapidly affords Cu nanoclusters (NCs). The as-prepared GSH-CuNCs possess a small size (∼2.2 ± 0.2 nm), red luminescence with quantum yield (5.3%), and water-dispersibility. Moreover, the fluorescence of the as-prepared GSH-CuNCs is responsive to pH so that the ...

The selective cultivation of bacteria by incorporating chemicals in the media depends on supplying a substance which either stimulates the growth of the species to be isolated or inhibits unwanted species. Tetrathionate is a good selector of Salmonellae in faeces culture, and is believed to act in both ways. Tetrathionate reducers, such as Salmonellae, flourish in broth containing it, whereas a...

We report a rapid one-pot supercritical fluid approach to prepare the desired size and morphology controlled LiMPO(4) nanocrystals, using oleylamine as both capping and reducing agent.

A rapid and efficient one-step approach to prepare graphene-Ag nanocomposites by simultaneous reduction of graphene oxide (GO) and silver ions with formaldehyde as the reducing agent within several minutes was demonstrated.

by negative contrast has shown lipid micelles that might be associated with mucin threads and which disappear after delipidation (Slayter et al., 1984). In rat small-intestinal mucins, different varieties of lipids aie bound to the different parts, naked or hyperglycosylated, of these mucins (Witas et al., 1983). At the present time, there is no published indication of such differences in human...