Bio-aromatics (benzene, toluene, xylenes, BTX) were prepared by the catalytic pyrolysis of six different black liquors using both in situ and ex situ approaches. A wide range of catalysts was screened and conditions were optimized in microscale reactors. Up to 7 wt % of BTX, based on the organic fraction of the black liquors, was obtained for both the in situ and ex situ pyrolysis (T = 500-600 ...

A comparative study of different species from the yeast genera Cyptococcus and Rhodotorula, isolated from rotted wood, was camed out using analytical pyrolysis-gas chromatography-mass spectrometry. The predominant compounds obtained were various alkanes, cyclic ketones, indolic compounds, alkanoic acids and furan derivatives, which are pyrolytic products of lipids, proteins and carbohydrates. T...

This paper describes a kinetic study of the decomposition of waste printed circuit boards (WPCB) under conventional and microwave-induced pyrolysis conditions. We discuss the heating rates and the influence of the pyrolysis on the thermal decomposition kinetics of WPCB. We find that the thermal degradation of WPCB in a controlled conventional thermogravimetric analyzer (TGA) occurred in the tem...

The radiative heat transfer problem is investigated numerically for 2D complex geometry biomass pyrolysis reactor composed of two pyrolysis chambers and a heat recuperator. The fumes are a mixture of carbon dioxide and water vapor charged with absorbing and scattering particles and soot. In order to increase gases residence time and heat transfer, the heat recuperator is provided with many incl...

The inherent nonlinearities in the kinetics and heat transfer models of biomass pyrolysis have led to the applications of various numerical methods in solving the nonlinear problems. However, in order to have physical insights into the phenomena and to show the direct relationships between the parameters of the models, analytical solutions are required. In this work, approximate analytical solu...

In the work presented here, nitrogen and sulfur co doped on porous graphene was synthesized using pyrolysis at 900°C for 2h and the hydrothermal technique at 180°C for 24h as metal-free electrocatalysts for oxygen reduction reaction (ORR) under alkaline conditions. All the materials have been characterized by Scanning Electron Microscopy (SEM) and X-ray photo-electron spectroscopy (XPS). Moreov...

Liquid products obtained by the fast pyrolysis process applied to biomass can be used as chemical raw materials and liquid fuels. In this study, tea bush, walnut shell, pine cone samples selected were from Trabzon Rize provinces in Eastern Black Sea Region used. When considered terms of our region, available waste are easy access have a high potential quantity. To employ them experimental inves...

The flaky graphites were prepared from lignite. The effects of phosphoric acid ratios and pyrolysis temperatures on flake formation were studied by SEM, TEM and XRD. The results showed that the flaky graphite occurred at a pyrolysis temperature of 600°C with a 1.0:1.0 ratio of carbon to phosphoric acid. The flaky formation was almost completed by pyrolysis at 800°C and with a 1:2.0 ratio of car...

The catalytic pyrolysis of Laminaria japonica was carried out over a hierarchical meso-MFI zeolite (Meso-MFI) and nanoporous Al-MCM-48 using pyrolysis gas chromatography/mass spectrometry (Py-GC/MS). The effect of the catalyst type on the product distribution and chemical composition of the bio-oil was examined using Py-GC/MS. The Meso-MFI exhibited a higher activity in deoxygenation and aromat...

the waste tyres represent a source of energy and valuable hydrocarbon products. waste tyres were pyrolysed catalytically in a batch reactor under atmospheric pressure. the effects of basic catalysts (mgo and caco3) were studied on the pyrolysis products. the distribution ratio of gas, liquid and char with mgo and caco3 were 24.4:39.8:35.8 wt % and 32.5:32.2:35.2 wt % respectively at 350°c for 2...