Poly(carbosilane) or PCS, {–CH2–SiH(CH3)–}n, is used as a Si-bearing precursor in combination with a coal tar pitch to study thermally induced transformations toward SiC-modified carbon composites. Following mixing of the components in the molten pitch at 160oC, the mixture is heated under argon atmosphere at 500oC yielding a solid carbonizate that is further subjected to separate pyrolysis exp...

The deposition of a thin tin oxide film allows for the manufacture of modern gas sensors. Spray pyrolysis deposition is used to grow the required thin films, as it can be seamlessly integrated into a standard CMOS processing sequence. A model for spray pyrolysis deposition is developed and implemented within the Level Set framework. Two models for the topography modification due to spray pyroly...

Graphene can be synthesized from polyacrylonitrile (PAN) polymer through pyrolysis. A metal catalyst such as nickel (Ni) is required for the conversion of the polymer to graphene. The metal catalysts can be placed either atop or underneath the polymer precursor. We observed that spatially non-uniform and disconnected graphene was fabricated when PAN film coated with a Ni layer was pyrolyzed, re...

The thermal degradation of tyrosine at a residence time of 0.2s was conducted in a tubular flow reactor in flowing N2 and 4% O2 in N2 for a total pyrolysis time of 3min. The fractional pyrolysis technique, in which the same sample was heated continuously at each pyrolysis temperature, was applied. Thermal decomposition of tyrosine between 350 and 550°C yielded predominantly phenolic compounds (...

Bark is one of the most under-utilized types of lignocellulosic biomass in the forest industry. In this study, bark fast pyrolysis was optimized for phenols yield using response surface methodology (RSM), considering the pyrolysis temperature, gas flow rate, and biomass particle size. The bio-oil generated under optimal conditions was then characterized by gas chromatography-mass spectrometry (...

−Three kinds of biochars (called poplar branch biochar (PBC), water hyacinth biochar (WHC), and corn straw biochar (CSC)) were prepared in a fixed-bed pyrolyzer at different pyrolysis temperature of 300-700 C. The effects of biochar species, pyrolysis temperature and biochar addition on adsorption characteristics of typical heavy metals (HMs) of Pb and Zn in vegetable soil (collected from lead-...

This report is preliminary and has not been reviewed for conformity with U. S. Geo'ogical Survey editorial standards (or with the North American Stratigraphic Code). Any use of trade, product, or firm names is for descriptive purposes only and does not imply endorsement by the U. S. Government. INTRODUCTION Predicting the gas:oil ratio (GOR) of a petroleum play or prospect is important in evalu...

Hypersonic flight over Mach 5 should be achieved with Supersonic Combustion Ramjet. The regenerative cooling presents the advantage to use the fuel as a coolant, which results in its pyrolysis. Both cooling channel and combustion chamber are studied numerically by coupling the transient phenomena with detailed pyrolysis and combustion chemistry (360 species and 2777 reactions). A Mach 6 flight ...

Fast pyrolysis of poplar wood followed with catalytic cracking of the pyrolysis vapors was performed using analytical pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS). The catalysts applied in this study were nano MgO, CaO, TiO2, Fe2O3, NiO and ZnO. These catalysts displayed different catalytic capabilities towards the pyrolytic products. The catalysis by CaO significantly reduced the ...