-Sorption isotherms for four gases (N2, A, Kr and C O 2 ) , commonly used in specific surface area and pore structure measurements, have been accurately determined on a number of clay mineral and oxide systems. Specific surface areas obtained by application of the BET theory to these isotherms illustrate the extent to which the apparent cross-sectional areas for these sorbed gases vary with sur...

The influence of nonlinear sorption and prior sorbate/ sorbent exposure time on transport of fenuron and monuron in laboratory soil columns was studied. Observed monuron breakthrough curves (BTCs) were well described using a two-region transport model with a single mass-transfer rate coefficient, independent of prior sorbate/sorbent exposure history. However, levels of soil-resident postelution...

In this work, styrene removal from wastewater by using sugarcane waste (bagasse) as an adsorbent was studied. Equilibrium isotherms and kinetics were determined; the effects of bagasse particle size and concentration, solutions pH, and temperature on the biosorption of styrene were studied in batch experiments. Adsorption equilibrium data was successfully fitted to Langmuir isotherms (R2=0.986)...

The degree, mechanisms, and kinetics of phosphorus (P) sorption onto soils can have a significant influence on leaching losses of P from soil. The objectives of this study were to measure the impact of retention time (RT) on P sorption in a flow-through system intended to simulate downward movement of a P solution through two different riparian soils, and determine if isothermal titration calor...

Retention of heavy metal ions on soil mineral surfaces is a crucial process for maintaining environmental quality. A thorough understanding of the sorption mechanisms of heavy metals on soil mineral surfaces is therefore of fundamental importance. This study examined Ni(Il) sorption mechanisms on pyrophyllite. The removal of Ni from solution was studied as a function of pH (pH = 5-8.5), initial...

The aim of this study was to remove Cd by ion-exchange resin Amberjet 1200H in flow condition. The adsorption characteristics of metal onto the resin were accurately described by Freundlich isotherms. The ion exchange of cadmium on resin follows pseudo-second-order kinetics. Ion exchange capacities of the cadmium on the ion exchange resin was studied in metal solution. The capacities of sorptio...

Amendments are frequently added to agricultural soils to increase organic matter content. In this study, we examined the influence of alperujo, an olive oil mill waste, on the availability of two triazine herbicides, terbuthylazine and atrazine, in two different sandy soils, one from Sevilla, Spain, and the other from Minnesota. The effect of aging on herbicide sorption and bioavailability was ...

In this study, activated carbon synthesized from Aloe vera green wastes was used as a sorbent to remove 4-chlorophenol (4-CP) from aqueous solutions. The influence of contact time (0-100 minutes), pH (2-8), adsorbent dosage (1-9 g/l), and initial 4-CP concentration (10-60 mg/l) in batch system was investigated on the sorption. The sorbent was specified using scanning electron microscopy (SEM). ...

the effect of 0, 2, and 5 mm of citric, malic and oxalic acids on phosphorus (p) sorption was evaluated. in the collected soils, the level of total calcium carbonate stood in the range of 4-28%, clay content at 33-56% and the amount of organic matter recorded within 0.6-2.7%. the results indicated that the addition of organic acids causes reduction in p sorption. citric acid in most soils, was ...

We present a non-destructive, reusable apparatus with which to measure physical adsorption isotherms of intact porous membranes. We developed a two-piece sample container to make reliable sorption measurements of porous membranes, the properties of which may differ from those of powders due to crystal intergrowth. This novel system employs a resealable container that can be immersed in a cryoge...