In view of a possible use as anode materials in acidic direct alcohol fuel cells, the electro-catalytic activity of Pt-Ni and Pt-M-Ni (M = Ru, Sn) catalysts for methanol and ethanol oxidation has been widely investigated. An overview of literature data regarding the effect of the addition of Ni to Pt and Pt-M on the methanol and ethanol oxidation activity in acid environment of the resulting bi...

Nanosized graphene quantum dots were prepared by acid etching of carbon fibers and used as effective substrate supports for platinum nanoparticles which were synthesized by thermolytic reduction of platinum(II) chloride in ethylene glycol. Transmission electron microscopic measurements showed that the resulting nanocomposite (Pt/G) particles exhibited an average diameter of 2.79 ± 0.38 nm, with...

SYNLETT 2005, No. 4, pp 0545–055904.03.2005 Advanced online publication: 22.02.2005 DOI: 10.1055/s-2005-862380; Art ID: A36604ST © Georg Thieme Verlag Stuttgart · New York Abstract: In this account, we survey our work on the use of transition metal nanoparticles as catalysts in Pauson–Khand-type reactions. Cobalt nanoparticles and Co/Ru, Co/Rh, and Co/Pd heterobimetallic nanoparticles have been...

In this work, large size (i.e., diameter > 100 nm) graphene tubes with nitrogen-doping are prepared through a high-temperature graphitization process of dicyandiamide (DCDA) and Iron(II) acetate templated by a novel metal-organic framework (MIL-100(Fe)). The nitrogen-doped graphene tube (N-GT)-rich iron-nitrogen-carbon (Fe-N-C) catalysts exhibit inherently high activity towards the oxygen reduc...

Butylphenyl-functionalized Pt nanoparticles (Pt-BP) with an average core diameter of 2.93 ± 0.49 nm were synthesized by the co-reduction of butylphenyl diazonium salt and H(2)PtCl(4). Cyclic voltammetric studies of the Pt-BP nanoparticles showed a much less pronounced hysteresis between the oxidation currents of formic acid in the forward and reverse scans, as compared to that on naked Pt surfa...

Platinum (Pt) nanoparticles were successfully electrodeposited in situ on an organic conductive polymer, poly(3,4-ethylenedioxythiophene) (PEDOT), using for the first time sinusoidal voltages of various frequencies in a chloroplatinic acid solution. The organic PEDOT matrix was electrodeposited on Pt electrode chips. The Pt electrode chips consist of a 150 nm Pt layer deposited on 100-oriented ...

Intermetallic Pt(3)Ti nanoparticles are solubilized in water by using a generation-five, hydroxyl-terminated, poly(amidoamine) dendrimer, G5OH, as a post-synthesis surfactant. Pt(3)Ti nanoparticles, encapsulated in G5OH and dispersed over the electrode surface, exhibited a superior catalytic activity toward the electro-reduction reaction of oxygen compared to as-prepared, highly agglomerated na...

Pt nanoparticles with controlled sizes between 1.6–7.0 nm were anchored onto the surface and pores of SBA-15 silica support. The catalysts were characterized by TEM-ED, BET, XRD, and ICP-MS techniques and were tested in liquid phase hydrosilylation of phenylacetylene with triethylsilane. The activity of the 7.0 nm Pt nanoparticles anchored onto the surface of SBA-15 in hydrosilylation (TOF = 0....

Hetero-nanoparticles represent a new class of nanomaterials exhibiting intriguing multifunctional and collective properties which could find applications in photovoltaics, fuel-cell catalysis, medical imaging and therapy, and electronics. In this paper, we report a novel polymer-single-crystal-templating (PSCryT) approach for the controllable synthesis of hetero-nanoparticles. 2D polymer single...

Composite electrodes consisting of Pt nanoparticles-supported on multiwalled carbon nanotubes grown directly on carbon paper (Pt/CNTs/carbon aper) have been synthesized by a new method using glacial acetic acid as a reducing agent. Transmission electron microscopy (TEM) images show hat the Pt nanoparticles with high density and relative small in size (2–4 nm) were monodispersed on the surface o...