Epoxies are often cured using primary and secondary amines in an efficient reaction catalyzed by tertiary amines. Through coordination effects, lower the transition-state energy enough to allow take place under ambient conditions. In this paper, we demonstrate how, conditions, bound close intramolecular proximity a amine able catalyze amine-epoxy reactions as well promote etherifications epoxy-...

A three-component coupling reaction of ortho-phthalaldehyde, 9,10-dihydro-9-oxa-10-phosphaphenanthrene 10-oxide, and various primary amines readily afforded novel phosphorus-substituted stable isoindoles in good to excellent yields. The importance the reversible ring-opening 10-oxide by methanolysis became apparent.

Over the years, methods have been developed for the preparation of quaternary ammonium compounds, which are important as organic intermediates, detergents, insecticides, bacteriostats, and drugs [1, 2]. The most common method for preparation of these compounds is by alkylation of tertiary amines [3, 4]. Primary and secondary amines have also been quaternized, albeit less frequently [3, 4], due ...

The reaction between CO(2) and aqueous amines to produce a charged carbamate product plays a crucial role in post-combustion capture chemistry when primary and secondary amines are used. In this paper, we report the low energy negative-ion CID results for several anionic carbamates derived from primary and secondary amines commonly used as post-combustion capture solvents. The study was perform...