The effects of seven macrocyclic compounds comprising four phthalocyanines (Pcs) namely 1,4,8,11,15,18,22,25-octabutoxy-29H,31H-phthalocyanine (Pc1), 2,3,9,10,16,17,23,24-octakis(octyloxy)-29H,31H-phthalocyanine (Pc2), 2,9,16,23-tetra-tert-butyl-29H,31H-phthalocyanine (Pc3) and 29H,31H-phthalocyanine (Pc4), and three naphthalocyanines namely 5,9,14,18,23,27,32,36-octabutoxy-2,3-naphthalocyanine...

The inhibition efficiency (IE) of the hydrochloride salt chitosan biguanidine (CBG-HCl, a green organic compound) on stainless steel alloy (SS) corrosion in 0.5 M H2SO4 solution was documented this work. Data reported for electrochemical impedance spectroscopy (EIS) and potentiodynamic analysis confirmed increasing resistance presence CBG-HCl with synergistic effect KI. Potentiodynamic experime...

The effects of H2SO4 concentration on the electrochemical behaviour of passive films formed on AISI 304 stainless steel were investigated using by potentiodynamic polarization, Mott–Schottky analysis and electrochemical impedance spectroscopy (EIS). Potentiodynamic polarization indicated that the corrosion potentials were found to shift towards negative direction with an increase in solution co...

Susceptibility of mild steel to corrosion attack has restricted its industrial applications, despite its numerous advantageous characteristics. Comparison of the inhibitive tendency of a mixture of zinc gluconate (ZG) and ferrous gluconate (FG) on the corrosion behavior of mild steel in acid and saline media was investigated using electrochemical and weight loss techniques. The FG:ZG ratio was ...

Laser surface modification of Ti-6Al-4V with an existing calcium phosphate coating has been conducted to enhance the surface properties. The electrochemical and mechanical behaviors of calcium phosphate deposited on a Ti-6Al-4V surface and remelted using a Nd:YAG laser at varying laser power densities (25-50 W/mm(2)) have been studied and the results are presented. The electrochemical propertie...

The corrosion resistance and biocompatibility of a novel Fe50Cr18Mo10C20Si2 metallic glass (Fe–MG), are studied by electrochemical measurements indirect contacting cytotoxicity assays for biomedical applications. In Hank’s solution, the Fe–MG shows better than SS316L, evidenced larger polarization in potentiodynamic impedance spectroscopy (EIS) tests, lower amounts released ions during immersio...

In this study, duplex surface treatments were used to prepare a ZrO2/Cr bilayer coating on zirconium alloy cladding for enhancing the wear and corrosion behaviors. The cross-section morphology of coated Zr-4 was characterized; results show that Cr- ZrO2/Cr-coated samples had similar morphology, more obvious undulates could be observed than pure Cr owing rough plasma electrolytic oxidation coati...