It is shown how the phase-space kinetic theory of polymeric liquid mixtures leads to a set of extended Maxwell-Stefan equations describing multicomponent diffusion. This expression reduces to standard results for dilute solutions and for undiluted polymers. The polymer molecules are modeled as flexible bead-spring structures. To obtain the Maxwell-Stefan equations, the usual expression for the ...

A generic noncovalent approach for dispersing high concentrations of individual single-walled carbon nanotubes (SWNT) in organic as well as aqueous solutions of synthetic block copolymers is presented. It is suggested that a weak, long-ranged entropic repulsion among polymer-decorated tubes acts as a barrier that prevents the tubes from approaching the attractive part of the intertube potential...

Polymeric alkylpyridinium salts (poly-APS) isolated from the marine sponge Reniera sarai act as potent anticholinesterase agents; in addition they show moderate hemolytic and cytotoxic activities. The hemolytic activity of poly-APS is due to their detergent-like structure and behavior in aqueous solutions. In this work, the hemolytic activity of poly-APS is analyzed and compared to that of stru...

A long-period grating (LPG) based compact optical fiber sensor working in reflection mode is demonstrated. A technique to make a mirror on the cladding region of a fiber end-face to reflect only the cladding modes was realized by growing a polymeric microtip on the core region of the fiber end-face, by photopolymerization, followed by coating the fiber end-face with an aluminum film. Using the ...

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Infrared absorption spectra of the precipitated solids separated from aluminiumhydroxide solutions below the pH of minimum solubility of AI(OH)3 demonstrate the slow ageing of polymeric A1 complexes to gibbsite. On comparison with the spectra of natural gibbsites, shifts in absorption frequency during crystal growth are interpreted in terms of changes in hydrogen bonding as a consequence of dep...

The large expansion of the robotic field in the last decades has created a growing interest in the research and development of tactile sensing solutions for robot hand and body integration. Piezoresistive composites are one of the most widely employed materials for this purpose, combining simple and low cost preparation with high flexibility and conformability to surfaces, low power consumption...

5,10,15,20-Tetraferrocenyl porphyrin, H2TFcP, a simple example of a donor-acceptor system, was tested as ligand for the development of a novel multi-transduction chemical sensors aimed at the determination of transition metal ions. The fluorescence energy transfer between ferrocene donor and porphyrin acceptor sub-units was considered. The simultaneously measured optical and potentiometric resp...

The developed bio-field effect transistor (BioFET) consists in nano-silver ink printed source and drain electrodes, a polymeric organic semiconductor, dielectric layer based on methyl methacrylate (MMA) and finally the reference electrode of silver-silver chloride ink. The thickness of the dielectric layer was optimized and characterized by Scanning Electron Microscopy (SEM) and by electrical m...

A 2-hydroxyazobenzene platform has been evaluated to photorelease protons in aqueous solutions. Three different systems relying on molecular, supramolecular and polymeric strategies have been investigated in order to tune the water solubility and the thermodynamic and kinetic properties. This paper first reports on the syntheses and the physico chemical analyses for each system. Subsequently, w...