There is strong interest in the research & development of the particle/polymer composite technology for functional applications. Current activities are directed towards polymer assisted synthesis of ultrafine metal or semiconductor particles in solution, with an ultimate goal to arrange the particles in a matrix in well-controlled fashion, for possible electro-optical applications. In the prese...

To develop a platform for tumor chemotherapy, poly(acrylic acid-co-methyl methacrylate) microparticles have been synthesized. Carboxylate containing monomers were included to complex therapeutic agents, specifically cisplatin. Microparticles were prepared by free radical emulsion polymerization in aqueous media. Particle diameter, zeta-potential, in vitro cytotoxicity, and in vivo acute toxicit...

† Center for Neutron Research, NIST. ‡ National Institutes of Health. § Polymers Division, NIST. * Corresponding author. E-mail [email protected]. National Institute of Standards and Technology, Center for Neutron Research, 100 Bureau Drive, Gaithersburg, Maryland 20899-8562; National Institutes of Health, NICHD, Laboratory of Integrative and Medical Biophysics, 13 South Drive, Bethesda, Maryla...

: a new fibrous adsorbent was prepared by grafting acrylic acid /acryl amide (aa/aam) co-monomers onto poly(ethylene terephtalat) (pet) fibers. the resulting sorbent has been characterized by fourier transform infrared spectroscopy (ft-ir), thermo gravimetric analysis (tga), scanning electron microscopy (sem) and elemental analysis and studied for the preconcentration and determination of trace...

The design, preparation, and properties of planar multilayer structures composed of various combinations of sequentially deposited polyelectrolyte (PE) chains and self-assembled layers of individual block copolymer aggregates (vesicles, micelles, or large compound micelles (LCMs)) are described. The aggregates contain negatively or positively charged corona chains while the PE multilayers conta...

We have used ultra-small-angle scattering (USANS) and fluorescence microscopy to demonstrate the existence of a nonfractal large-scale structure in attractive micellar gels of poly(styrene)-poly(acrylic acid) block copolymers, which have some characteristics of attractive colloidal glasses. The nature of the large-scale structure appears to depend systematically on the strength of attraction. O...

The present study aims to develop a pH thermosensitive nanocarriers as drug delivery system better controll release. Nanoparticles was developed by the combination of smart polymers, chitosan and poly(acrylic acid) were chosen biodegradable vectors encapsulate transport drug. used method based on polymerization acrylic acid using reticulated template. Analysis particle size, Zeta potential, siz...

Silica coated silver (Ag@SiO2) nanoparticles were prepared and characterized by transmission electron microscope (TEM) and UV-vis absorption, and the nanoparticles were used as labels in sandwich-type immunosensor of Escherichia coli O157:H7 (E. coli O157:H7). The labels involved in immunoreaction were dissolved by mixed acid of hydrofluoric acid and nitric acid, and the released Ag(+) ions wer...

The present study is aimed at developing novel type of interpenetrating polymeric network (IPN) hydrogels of chitosan with poly(acrylic acid) for the controlled release of amphetamine drug. IPN hydrogels were synthesized by simultaneous polymerization/crosslinking of acrylic acid monomer in the presence of chitosan and crosslinker. The swelling properties and in vitro drug release characteristi...

Bioactive glasses (BG) are used to regenerate bone, as they degrade and release therapeutic ions. Glass ionomer cements (GIC) are used in dentistry, can be delivered by injection, and set in situ by a reaction between an acid-degradable glass and a polymeric acid. Our aim was to combine the advantages of BG and GIC, and we investigated the use of alkali-free BG (SiO2–CaO–CaF2–MgO) with 0–50% of...