The neutron-deficient Bi188 and Po188 isotopes have been studied by γ-ray spectroscopy using the recoil-decay tagging technique with Argonne Gas-Filled Analyzer. A new 0.25(5)-μs isomeric state a prompt cascade formed 319-, 366-, 462-keV γ rays established on top of (10−) α-decaying isomer in Bi188. first excited (2+) was identified, its excitation energy 242(2) keV continues nearly constant tr...