نتایج جستجو برای: photo oxidation
تعداد نتایج: 144058 فیلتر نتایج به سال:
Recently, intensive efforts are dedicated to convert and store the solar energy in a single device. Herein, dye-synthesized solar cell technology is combined with lithium-ion materials to investigate light-assisted battery charging. In particular we report the direct photo-oxidation of lithium iron phosphate nanocrystals in the presence of a dye as a hybrid photo-cathode in a two-electrode syst...
Many researchers have reported on obtaining TiO2 thin films, using different methods [1-7]. These extensive studies on TiO2 have been due to the importance of these films in variety of applications including low-loss, low-scatter optical coating for visible and near infrared optics [8-11] and electrical devices [12,13]. These applications have stimulated a considerable amount of activity in fab...
In this study, a microwave/UV/TiO(2)/ozone/H(2)O(2) hybrid process system, in which various techniques that have been used for water treatment are combined, is evaluated to develop an advanced technology to treat non-biodegradable water pollutants efficiently. In particular, the objective of this study is to develop a novel advanced oxidation process that overcomes the limitations of existing s...
Novel 9alpha and 9beta-hydroxy grayanotoxin II derivatives were prepared by photo-sensitized oxygenation of iso-grayanotoxin II and oxidation of grayanotoxin II tetraacetate with selenium dioxide respectively. The lethal dosage of 9alpha and 9beta-hydroxy grayanotoxin II were lower than that of grayanotoxin II. In addition, the lethal dosage of 9beta-hydroxy-dihydro grayanotoxin II was higher t...
An efficient procedure for preparing enantiopure polycyclic ethers is reported. The protocol is based on the photo-oxidation/conjugate addition sequence over a chiral functionalized furan, which was prepared from commercially available tri-O-acetyl-D-glucal. The Michael addition step afforded two products with the same absolute configuration from a mixture of diastereomers.
Visible-light-derived O(2) production was yielded by conjugating water oxidation catalysis by [(OH(2))(terpy)Mn(μ-O)(2)Mn(terpy)(OH(2))](3+) as an oxygen evolving center model and photo-sensitization of [Ru(bpy)(3)](2+) as a photoexcitation center model at an interlayer of mica.
The sensitized photo-oxidation of amino acids in proteins is a special case of chemical modification, which is used in particular to study buried and exposed groups in proteins. The general principles of the technique and various applications of it are discussed in this article.
Hyperbranched nanostructured bismuth vanadate at a chemically polarized water/organic interface is applied for efficient visible light-driven catalytic oxidation of water in the presence of [Co(bpy)3](PF6)3 as an organic soluble electron acceptor. The photocurrent response originating from the transfer of photo-excited electrons in BiVO4 to [Co(bpy)3]3+ is measured by scanning electrochemical m...
In the stratosphere, the ozone (O3) plays a role of natural and beneficial screen in relation to the harmful effects of ultraviolet (UV) for the organic matter (= good ozone). In the troposphere, O3 is a pollutant that is produced during the atmospheric photo-oxidation of ozone precursors: Volatile Organic Compounds (VOCs) and nitrogen oxides (NOx) mainly emitted by anthropogenic activities (= ...
Photosynthetic electron flow in the bacterium Rhodopseudomonas sphaeroides involves two c-type cytochromes, one membrane-bound and the other a soluble protein, cytochrome c2. Membranes deficient in cytochrome c2 were used for photo-oxidation studies, with and without the addition of purified cytochrome c2. The results favour a series interrelation, membrane cytochrome c-cytochrome c2-reaction c...
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