Silicon has been widely considered as the next generation anode material for lithium-ion batteries, due to its substantially higher capacity compared to conventionally used graphite. However, silicon-based electrodes suffer from problems such as poor capacity retention and low coulombic efficiency. Significant amount of work has been devoted to improve the performance of silicon electrodes. Amo...

The magnetites and sulfides located in the rims of carbonate globules in the Martian meteorite ALH84001 have been claimed as evidence of past life on Mars. Here, we consider the possibility that the rims were formed by dissolution and reprecipitation of the primary carbonate by the action of water. To estimate the rate of these solution-precipitation reactions a kinetic model of magnesite-sider...

Our previous research has demonstrated that dissolved organic matter (DOM) influences calcium carbonate mineral formation in surface and ground water. To better understand DOM mediation of carbonate precipitation and DOM co-precipitation and/or incorporation with carbonate minerals, we characterized the content and speciation of DOM in carbonate minerals and in the lake water of Pyramid Lake, N...

An ancient Martian hydrosphere consisting of an alkali-rich ocean would likely produce solid carbonate minerals through the processes of evaporation and/or freezing. We postulate that both (or either) of these kinetically-driven processes would produce carbonate minerals whose stable isotopic compositions are highly fractionated (enriched) with respect to the source carbon. Various scenarios ha...

The complexation of Cm(III) with transferrin is investigated in the pH range from 3.5 to 11.0 in the absence of carbonate and at c(carbonate)tot = 25 mM. In the absence of carbonate two Cm(III) transferrin species I and II are formed depending on pH. An increase of the total carbonate concentration favors the formation of the Cm(III) transferrin species II with Cm(III) bound at the Fe(III) bind...

9 We report oxygen and carbon isotope results of bulk and detrital carbonate grains 10 from the last glaciation at IODP Site U1308 (re-occupation of DSDP Site 609). Oxygen 11 isotopic values of individual detrital carbonate grains from Heinrich events average 12 -5.4‰±1.3‰, presumably reflecting values of limestone and dolomite derived from 13 lower Paleozoic basins in northern Canada and north...

Introduction: Carbonaceous chondrites ALH84051 and ALH84034 rank amongst the most aqueously altered meteorites within the CM group and have been classified as petrologic type 1s. Nearly all primary anhydrous minerals have been replaced by secondary alteration phases, yet these meteorites still possess primitive whole-rock compositions [1,2]. Although elemental transport does not appear to have ...

Climate change is one of the greatest threats to the long-term maintenance of coral-dominated tropical ecosystems, and has received considerable attention over the past two decades. Coral bleaching and associated mortality events, which are predicted to become more frequent and intense, can alter the balance of different elements that are responsible for coral reef growth and maintenance. The g...