Topographic images of [Fe(Htrz)₂(trz)](BF₄) nanoparticles were acquired across the first-order spin transition using variable-temperature atomic force microscopy (AFM) in amplitude modulation mode. These studies revealed a complex morphology of the particles consisting of aggregates of small nanocrystals, which expand, separate and re-aggregate due to the mechanical stress during the spin-state...

Tungsten oxide (WO3) nanorods array prepared using chemical vapor deposition techniques was studied. The influence of oxygen gas concentration on the nanoscale tungsten oxide structure was observed; it was responsible for the stoichiometric and morphology variation from nanoscale particle to nanorods array. Experimental results also indicated that the deposition temperature was highly related t...

Polypyrrole–hydroxyethylcellulose/TitaniumDioxide (PPy-HEC/TiO2) nanocomposite was synthesized via in situ chemical oxidative polymerization method at room temperature in water and water/ethyl acetate solution in the presence of ferric chloride (FeCl3). The effect of TiO2 nanoparticles and HEC on the characteristics of products such as thermal stability and morphology was investigated. The fabr...

Tellurium (Te) nanostructures have been successfully synthesized via a simple hydrothermal methodfrom the reaction of a TeCl4 aqueous solution with thioglycolic acid (TGA) as a reductant. TGA can be easily oxidized to the corresponding disulfide [SCH2CO2H]2, which in turn can reduce TeCl4 to Te. The obtained Te was characterized by XRD, SEM, EDS, and DRS. The effect of reducing agent on morphol...

In this study chemical method of dissolution-Precipitation was applied to produce amorphous silica nanoparticles from rice straw ash (RSA), the waste material of rice cultivation. The morphology, particle size, structure and area of specific surface of synthesized amorphous silica nanoparticles were evaluated using transmission electron microscopy (TEM), X-ray diffraction analysis (XRD) and BET...

Oxidation of cyclooctene was studied in presence aqueous hydrogen peroxide (30%, v/v) over nano iron oxide. The catalyst prepared by microemulsion method and characterized using various techniques including XRD, TEM and BET techniques for evaluating phase, structure and morphology and surface area. In this study, we investigated the effects of varying the catalyst content, reaction temperature,...

Sphere-like cadmium molybdate (CdMoO4) nanostructures have been synthesized by a large scale and simple sonochemical method by using Cd(Sal)2 (Sal=salicylidene) and Na2MoO4.2H2O for the first time. The effects of sonochemical irradiation time, sonochemical power, temperature, solvent, surfactant and cadmium source were considered to obtain a controlled shape. The as-prepared nanostructured cadm...

With the increasingly development of automobile, electronics, aviation, spaceflight and other industries, it has put forward higher and higher requirements on the quality of molybdenum powder metallurgy products. Therefore, it is required that molybdenum powder should have better performance in chemical composition, physical morphology, average particle size, particle size distribution, apparen...

in this research, cuo spherical-like nanoparticles were synthesized using the planetary ball mill method. the structure, particle size and morphology of the resulting cuo nanoparticles were characterized by xrd (x-ray diffraction), sem (scanning electron microscopy) and saxs (small-angle x-ray scattering) methods. the results of this investigation showed that the smallest particles which were o...

Designable media can control properties of nanocomposite materials by spatially organizing nanoparticles. Here we theoretically study particle organization by ultrathin polymer films of grafted chains ("brushes"). Polymer-soluble nanoparticles smaller than a brush-determined threshold disperse in the film to a depth scaling inversely with particle volume. In the polymer-insoluble case, aggregat...