Shape and size of the synthesized NiO nano-sheets were retained during transformation of sheet-like b-Ni(OH)2 to NiO at elevated temperatures via nano-sized zirconia coating on the surface of b-Ni(OH)2. The average grain size was 6.42 nm after 600 C treatment and slightly increased to 10 nm after 1000 C treatment, showing effective sintering retardation between NiO nano-sheets. The excellent th...

ABSTRACT Infrared spectroscopy has been employed for a detailed characterization of ZrO2 and CeO2/ZrO2 supported nickel and copper/nickel catalysts to be utilized for methane decomposition. Adsorption of CO at 303 K was performed in order to determine the surface composition and accessible adsorption sites. Alloy formation occurred during reduction, as indicated by a red-shift of the vibrationa...

Electrochemical analysis allows in situ characterization of solid oxide electrochemical cells (SOCs) under operating conditions. However, the SOCs that have been analyzed in this way have ill-defined or uncommon microstructures in terms of porosity and tortuosity. Therefore, the nano-scale characterization of SOCs with respect to three-phase boundaries has been hindered. We introduce novel in s...

Uncovering microstructure evolution mechanisms that accompany the long-term operation of solid oxide fuel cells is a fundamental challenge in designing more durable energy system for future. To date, study cell stack degradation has focused mainly on electrochemical performance and, rarely, averaged microstructural parameters. Here we show an alternative approach which three-dimensional feature...

Sulfonic acid-functionalized polymer electrolyte membranes alternative to Nafion(®) were developed. These were hydrocarbon systems, such as blend sulfonated polyetheretherketone (s-PEEK), new generation perfluorosulfonic acid (PFSA) systems, and composite zirconium phosphate-PFSA polymers. The membranes varied in terms of composition, equivalent weight, thickness, and filler and were investigat...

The mechanical stability is an important phenomenon which governs many applications based properties of membranes. The inorganic materials of membrane may have been synthesized by qualitative the novel sol-gel or co-precipitation methods of material synthesis. The mMembranes of cobalt (CP) and nickel (NP) composites have been was designed by mixing of the polyvinyl chloride (PVC) with cobalt ph...

Water loss and the coincident increase in membrane resistance to proton conduction are significant barriers to high performance operation of traditional proton exchange membrane fuel cells at elevated temperatures where the relative humidity may be reduced. We report here approaches to the development of high temperature membranes for proton exchange membrane fuel cells; composite perfluorinate...

An ion-associate phase (IAP) microextraction/ back-microextraction system was applied for the enrichment, separation, and detection of trace amounts nickel from environmental water samples. Thenoyltrifluoroacetone (HTTA) acted not only as a chelating reagent nickel, but also component extraction phase, i.e., IAP. Nickel in 40 mL sample solution pH-adjusted with phenolsulfonate (PS−) tetramethyl...

background: some particular areas contain natural radionuclide at levels much higher than those usually present in earth's crust. the radiological impact of the use of zirconium ore in zirconium industry is due to internal exposure of the lung by alpha particles and external exposure of the body by the gamma rays. the result of gamma spectrometry measurement of the concentrations of the na...

Approximately 10% of the population in the USA suffer from nickel allergy, and many are unable to wear jewellery or handle coins and other objects that contain nickel. Many agents have been developed to reduce the penetration of nickel through skin, but few formulations are safe and effective. Here, we show that applying a thin layer of glycerine emollient containing nanoparticles of either cal...