(Me2CF3CO)2(Ar′N)WdW(NAr′)(OCMe2CF3)2 (Ar′ ) 2,6-Me2C6H3) reacts immediately at room temperature with 1 equiv of CCl4 to give the sparingly soluble [W(OCMe2CF3)2Cl]2(μ-NAr′)2. [W(NAr′)(OCMe2CF3)2]2 forms 1:1 adducts with simple donor ligands such as PMe3, PPhMe2, and pyridine, in which the base is likely to be coordinated to a single W center. Addition of ethylene to [W(NAr′)(OCMe2CF3)2]2 yield...

Nitrate reductase (nar) A, B and E mutants of Escherichia coli with plasmids carrying Klebsiella pneumoniae nitrogen fixation (nif) genes reduced acetylene independently of added molybdate, but nar D mutants showed pleiotropic dependence on the concentration of added molybdate for expression of both nar and nif. No complementation of nar mutations by nif occurred; nitrite but not nitrate repres...

Nitrogen loss after urea application and the low nitrogen utilization rate of plants are major issues in fertilizer application. We therefore adopted a combination 3,4-dimethylpyrazole phosphate (DMPP) applications order to investigate response DMPP ‘sweet sapphire’ (V. vinifera L.) grape seedlings growth. Three combinations were tested screen suitable concentrations for seedlings’ Transcriptom...

Utilization of naturally-occurring dissolved free and combined amino acids (DFAA and DCAA) and dissolved DNA (D-DNA) was studied in batch cultures of bacteria from 2 shallow marine environments, Santa Rosa Sound (SRS), Florida. USA, and Flax Pond (FP), Long Island, New York, USA. In addition to control experiments, cultures were enriched with various sources of C and N. In the SRS cultures, net...

Addition of ethylene to Mo(NAr)(CHCMe2Ph)(OHIPT)(Pyr) (NAr = N-2,6-i-Pr2C6H3, OHIPT = O-2,6-(2,4,6-i-Pr3C6H2)2C6H3, Pyr = NC4H4) led to the trigonal bipyramidal metallacyclobutane complex, Mo(NAr)(C3H6)(OHIPT)(Pyr), in which the imido and aryloxide ligands occupy axial positions. Mo(NAr)(C3H6)(OHIPT)(Pyr) loses ethylene to give isolable Mo(NAr)(CH2)(OHIPT)(Pyr). W(NAr)(CH2)(OTPP)(Me2Pyr) (OTPP ...

The expression and activity of glutamine synthetase (GS, EC 6.3.1.2) were examined in relation to the rate of CO2 assimilation in sun ̄ower (Helianthus annuus L.) leaves. Intact plants were kept in the dark for 72 h and subsequently exposed to light under different atmospheric CO2 concentrations (100, 400 and 1200 ml l) for 6 h. The in vivo rates of net CO2 assimilation correlated with atmospher...

mungbean (vigna radiata (l.) wilczek) or green gram as a dryland grain legume is exposed to varied timings and severity of drought stress, resulting in variability in photoassimilate production. in order to evaluate some physiological responses in one mungbean cultivar to timing and severity of drought stress, a 3-replicate rcbd (randomized complete block design) field experiment was carried ou...

The expression and activity of glutamine synthetase (GS, EC 6.3.1.2) were examined in relation to the rate of CO2 assimilation in sunflower (Helianthus annuus L.) leaves. Intact plants were kept in the dark for 72 h and subsequently exposed to light under different atmospheric CO2 concentrations (100, 400 and 1200 microl l-1) for 6 h. The in vivo rates of net CO2 assimilation correlated with at...

Estrogen receptor (ER) antagonists such as tamoxifen (Tam) have been used successfully to treat ER+ breast cancers for more than 30 years. Unfortunately, long term use of Tam can result in resistance. Tam resistance is associated with the activation of growth factor signaling pathways that promote cell proliferation and survival. The mitogen-activated protein kinase (MAPK), is up-regulated in T...

Retrieved profiles of temperature, water vapor, and cloud liquid water are obtained through neural net inversions of the brightness temperatures, where the neural net is trained using radiosonde soundings and corresponding forward modeled brightness temperatures. An observation operator has also been developed for the direct assimilation of the measured brightness temperatures, using the forwar...