In our manuscript, we assumed, that each substitutional Fe atom and each interstitial Fe atom, which exist with the ratio of 85% and 15% of the doped Fe atoms, respectively, contribute equally to the integrated XAS intensity expressed by equation (1) in the main text. Hereinafter, we call this assumption as assumption A in this Supplemental Information. This was used for deriving the following ...

The effect of small amounts of ruthenium on the formation of magnetite in highly alkaline media was investigated using X-ray powder diffraction (XRD), Mössbauer and FT-IR spectroscopies, field emission scanning electron microscopy (FE-SEM) and energy dispersive X-ray spectroscopy (EDS). Acicular a-FeOOH particles precipitated in a highly alkaline medium with the addition of tetramethylammonium ...

The marine cyanobacterium Trichodesmium sp. accounts for approximately half of the annual 'new' nitrogen introduced to the global ocean but its biogeography and activity is often limited by the availability of iron (Fe). A major source of Fe to the open ocean is Aeolian dust deposition in which Fe is largely comprised of particles with reduced bioavailability over soluble forms of Fe. We report...

production of fe-c alloy powders by mechanical alloying was studied. fe and graphite elemental powdermixtures containing 0.8 and 1.5wt.% graphite were mechanically alloyed using a planetary ball mill. thestructural changes of powder particles during mechanical alloying were studied by x-ray diffractometery,scanning electron microscopy and microhardness measurements. for both compositions, mecha...

The influence of Fe(III) starting material on the ability of magnetically recoverable biogenic magnetites produced by Geobacter sulfurreducens to retain metal oxyanion contaminants has been investigated. The reduction/removal of aqueous Cr(VI) was used to probe the reactivity of the biomagnetites. Nanomagnetites produced by the bacterial reduction of schwertmannite powder were more efficient at...

on carbon. These particles can interact with the active sites of the carbon to form a species a t the metal-carbon interface which is stable against high-temperature reduction. This interaction may occur via oxygen atoms bonding with both the carbon surface and iron atoms contacting the carbon. This oxygen could be provided by dissociation of the C O ligands during decomposition. The remainder ...

BACKGROUND There are many communities around the world that are exposed to high levels of particulate matter <10 µm (PM₁₀) of geogenic (earth derived) origin. Mineral dusts in the occupational setting are associated with poor lung health, however very little is known about the impact of heterogeneous community derived particles. We have preliminary evidence to suggest that the concentration of ...